213349

Ammoniumbromid

ACS reagent, ≥99.0%

• Lineare Formel: NH₄Br
• CAS-Nummer: 12124-97-9
• Molekulargewicht: 97.94
• EG-Nummer: 235-183-8
• MDL-Nummer: MFCD00011419
• UNSPSC-Code: 12352302
• eCl@ss: 38050407
• PubChem Substanz-ID: 329752145
• NACRES: NB.24

Eigenschaften

• Qualität: ACS reagent
• Dampfdruck: 1 mmHg ( 198.3 °C)
• Assay: ≥99.0%
• Form: powder or crystals
• Verunreinigungen: ≤0.005% insolubles
• Glührückstand: ≤0.01%
• pH-Wert: 4.5-6.0 (25 °C, 5%)
• mp (Schmelzpunkt): 452 °C (lit.)
• Dichte: 2.43 g/mL at 25 °C (lit.)
• Anionenspuren: bromate (BrO₃^-): ≤0.002%; chloride (Cl^-): ≤0.2%; iodide (I^-): ≤0.005%; sulfate (SO₄^2-): ≤0.005%
• Kationenspuren: Ba: ≤0.002%; Fe: ≤5 ppm; heavy metals: ≤5 ppm (by ICP-OES)
• SMILES String: N.Br[H]
• InChI: 1S/BrH.H3N/h1H;1H3
• InChIKey: SWLVFNYSXGMGBS-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Laser excited Raman spectral study reveals that 1?0 torsional transitions of the NH₄⁺ ion in phase III of NH₄Br were observed at 331cm^-1. Neutron diffraction studies have been conducted to evaluate the P-T phase diagram of NH₄Br and its deuterated form (ND₃Br).

Anwendung

Ammonium bromide may be used in the preparation of organic ammonium tribromides. It may also be used as a reagent during the transformation of benzyl derivatives of halides, amines, alcohols, and aldehydes into respective nitriles via oxidation.

Sicherheitshinweise

• Piktogramme: GHS08,GHS07
• Signalwort: Danger
• H-Sätze: H319,H336,H360FD,H362,H372
• P-Sätze: P202 - P260 - P263 - P264 - P305 + P351 + P338 - P308 + P313
• Gefahreneinstufungen: Eye Irrit. 2 - Lact. - Repr. 1B - STOT RE 1 - STOT SE 3
• Zielorgane: Central nervous system, Nervous system
• Lagerklassenschlüssel: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 1
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable