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123226

Sigma-Aldrich

Anisol

ReagentPlus®, 99%

Synonym(e):

Methoxybenzol, Methylphenylether

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About This Item

Lineare Formel:
CH3OC6H5
CAS-Nummer:
100-66-3
Molekulargewicht:
108.14
Beilstein:
506892
EG-Nummer:
202-876-1
MDL-Nummer:
MFCD00008354
UNSPSC-Code:
12352112
eCl@ss:
39023603
PubChem Substanz-ID:
329749709
NACRES:
NA.21
bp:
154 °C (lit.)
Preise und Verfügbarkeit sind derzeit nicht verfügbar.

Dampfdichte

3.7 (vs air)

Qualitätsniveau

200

Dampfdruck

10 mmHg ( 42.2 °C)

Produktlinie

ReagentPlus®

Assay

99%

Form

liquid

Selbstzündungstemp.

887 °F

Expl.-Gr.

0.34-6.3 %

dilution

(for general lab use)

Brechungsindex

n20/D 1.516 (lit.)

bp

154 °C (lit.)

mp (Schmelzpunkt)

−37 °C (lit.)

Dichte

0.995 g/mL at 25 °C (lit.)

SMILES String

COc1ccccc1

InChI

1S/C7H8O/c1-8-7-5-3-2-4-6-7/h2-6H,1H3

InChIKey

RDOXTESZEPMUJZ-UHFFFAOYSA-N

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Verwandte Kategorien

Allgemeine Beschreibung

Anisole can be obtained from the reaction between methyl formate and sodium phenolate or potassium phenolate at high temperature and pressure.[1]

Anwendung

Anisole has been used as a dopant to improve the sensitivity of photoionization at atmospheric pressure, which can be used as a source in the detection of nonpolar compounds using liquid chromatography coupled with mass spectrometry.[2] It has also been used to improve the molecular fragmentation which further increases the background signal intensity in hyperthermal surface ionization source, when coupled with time-of-flight mass spectrometer.[3]

Rechtliche Hinweise

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Piktogramme

FlameExclamation mark
GHS02,GHS07

Signalwort

Warning

H-Sätze

H226,H336

Gefahreneinstufungen

Flam. Liq. 3 - STOT SE 3

Zielorgane

Central nervous system

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 2

Flammpunkt (°F)

109.4 °F - closed cup

Flammpunkt (°C)

43 °C - closed cup

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
SDBB2653
MKCX2262
MKCW4043
MKCW5206
STBL3948

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Adolfsson H, et al.
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 37 (2014)
"A silica-based monolithic column in capillary HPLC and CEC coupled with ESI-MS or electrospray-atmospheric-pressure laser ionization-MS"
Droste S, et al.
Electrophoresis, 26(21), 4098-4103 (2005)
"Hyperthermal surface ionization in a time-of-flight mass spectrometer"
Weickhardt C and Draack L
Eur. J. Mass Spectrom., 6(4), 319- 323 (2000)
Adam F Lee et al.
Dalton transactions (Cambridge, England : 2003), 39(43), 10473-10482 (2010-10-05)
Size-controlled, catalytically active PVP-stabilised Pd nanoparticles have been studied by operando liquid phase XAS during the Suzuki cross-coupling of iodonanisole and phenylboronic acid in MeOH-toluene using KOMe base. XAS reveals nanoparticles are stable to metal leaching throughout the reaction, with
Shouhui Zhang et al.
The Journal of organic chemistry, 75(19), 6732-6735 (2010-09-09)
A CuI-catalyzed direct access to sulfides from disulfides via C-H bond cleavage of di- or trimethoxybenzene is described. The procedure utilizes O(2) as a clean and cheap oxidant. Direct selenation of the C-H bond also took place under this procedure.
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 Antwort

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 Antwort

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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