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Merck

87708

Supelco

Tetramethylammoniumbromid

suitable for ion pair chromatography, LiChropur, ≥99.0% (AT)

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About This Item

Lineare Formel:
(CH3)4N(Br)
CAS-Nummer:
Molekulargewicht:
154.05
Beilstein:
3620955
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12000000
PubChem Substanz-ID:
NACRES:
NB.21

Beschreibung

cationic

Qualitätsniveau

Assay

≥99.0% (AT)

Form

crystals

Qualität

LiChropur

Methode(n)

ion pair chromatography: suitable

mp (Schmelzpunkt)

>300 °C (lit.)

λ

10 % in H2O

UV-Absorption

λ: 240 nm Amax: 0.06
λ: 250 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02

Eignung

corresponds to standard for filter test

SMILES String

[Br-].C[N+](C)(C)C

InChI

1S/C4H12N.BrH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1

InChIKey

DDFYFBUWEBINLX-UHFFFAOYSA-M

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Allgemeine Beschreibung

Ion-pairing reagents, when used as mobile phase additives, promote the analysis of ionic and highly polar substances on reversed phase HPLC columns. The purity of mobile phase additives is of highest significance for their effective application. Sigma-Aldrich makes available a variety of tailor-made reagents for anionic (quaternary ammonium and phosphonium salts) and cationic (alkanesulfonates) separations. All mobile phase additives are tested thoroughly with special consideration on the demands of modern reversed phase HPLC:

Anwendung


  • pH Standardization in Analytical Chemistry: Buffers serve as critical components in the batch-to-batch reproducibility studies for primary pH methods, ensuring high precision in pH measurement across various scientific disciplines, from pharmaceuticals to environmental science (Asakai et al., 2024).



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Rechtliche Hinweise

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Piktogramme

Skull and crossbones

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Acute Tox. 2 Oral

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Potassium homeostasis is crucial for living cells. In the yeast Saccharomyces cerevisiae, the uptake of potassium is driven by the electrochemical gradient generated by the Pma1 H(+)-ATPase, and this process represents a major consumer of the gradient. We considered that
Qin Chen et al.
Bioresource technology, 117, 186-192 (2012-05-23)
The aim of this study was to explore the synergies of laccase, a ligninolytic enzyme, with cellulose and hemicellulase amendments on ensiled corn stover. Molecular signals of lignin decomposition were observed by tetramethylammonium hydroxide thermochemolysis and gas chromatography-mass spectroscopy (TMAH-GC-MS)
Maggie Tam et al.
The Analyst, 136(15), 3098-3106 (2011-06-24)
A novel analytical method, called Liquid Phase Ion Mobility Spectrometry (LiPIMS) was demonstrated, where aqueous phase analytes were ionized and introduced into non-aqueous liquids, transported by an external electric field from the point of generation to a collection electrode. Ions
Hui Chong et al.
Langmuir : the ACS journal of surfaces and colloids, 28(4), 2091-2098 (2011-11-08)
A new water-soluble conjugated polymer containing fluorene and boron-dipyrromethene repeat units in the backbones (PBF) that exhibits red emission was synthesized and characterized. Cationic PBF forms uniform nanoparticles with negatively charged disodium salt 3,3'-dithiodipropionic acid (SDPA) in aqueous solution through
Federica Maraschi et al.
Analytical biochemistry, 426(2), 142-146 (2012-05-01)
This article presents the first results demonstrating that total silicon trace concentration in human ventricular whole blood may be used as a further marker in the diagnosis of drowning. The difference in silicon content between the left and right ventricles

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