71478

N_α-(2,4-Dinitro-5-fluorophenyl)-L-alaninamid

for chiral derivatization, LiChropur^™, ≥99.0%

• Synonym(e): FDAA, Marfey-Reagenz
• Empirische Formel (Hill-System): C₉H₉FN₄O₅
• CAS-Nummer: 95713-52-3
• Molekulargewicht: 272.19
• Beilstein: 6820069
• MDL-Nummer: MFCD00042049
• UNSPSC-Code: 12000000
• PubChem Substanz-ID: 329763313
• NACRES: NA.22

Eigenschaften

• Qualität: derivatization grade ((chiral)); for chiral derivatization; LiChropur^™
• Qualitätsniveau: 100
• Assay: ≥99.0% (sum of enantiomers, TLC); ≥99.0%
• Form: powder
• Optische Aktivität: [α]20/D +56±2°, c = 1% in acetone
• Optische Reinheit: enantiomeric ratio: ≥99.5:0.5 (HPLC)
• Methode(n): HPLC: suitable
• Lagertemp.: 2-8°C
• SMILES String: C[C@H](Nc1cc(F)c(cc1[N+]([O-])=O)[N+]([O-])=O)C(N)=O
• InChI: 1S/C9H9FN4O5/c1-4(9(11)15)12-6-2-5(10)7(13(16)17)3-8(6)14(18)19/h2-4,12H,1H3,(H2,11,15)/t4-/m0/s1
• InChIKey: NEPLBHLFDJOJGP-BYPYZUCNSA-N

Beschreibung

Allgemeine Beschreibung

N_α-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide (FDAA) is a chiral derivatizing agent (CDA), has high enantioselectivity but low sensitivity as compared to other CDAs. It is generally used to assign the stereochemistry of amino acids in trace amounts.[1]

Anwendung

FDAA was used as derivatizing reagent, in a study performed to understand unusual amino acids using reversed phase high performance liquid chromatography-electrospray ionization mass spectrometry (RPHPLC-ESI-MS).[1]

Sonstige Hinweise

Derivatisierungsreagenz für die Analyse ungewöhnlicher chiraler α-Aminosäuren-Analoga[2]

Empfohlene Produkte

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Rechtliche Hinweise

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves