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42604

Sigma-Aldrich

Glycine-tert-butylester -hydrochlorid

puriss., ≥99.0% (AT)

Synonym(e):

tert-Butyl aminoacetate hydrochloride

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About This Item

Lineare Formel:
H2NCH2CO2C(CH3)3 · HCl
CAS-Nummer:
27532-96-3
Molekulargewicht:
167.63
Beilstein:
3989048
MDL-Nummer:
MFCD00058255
UNSPSC-Code:
12352200
eCl@ss:
32160406
PubChem Substanz-ID:
329756247
NACRES:
NA.22

Qualität

puriss.

Qualitätsniveau

100

Assay

≥99.0% (AT)

Form

solid

Eignung der Reaktion

reaction type: solution phase peptide synthesis

mp (Schmelzpunkt)

141-143 °C (lit.)

Löslichkeit

H2O: 0.1 g/mL, clear, colorless

Anwendung(en)

peptide synthesis

SMILES String

Cl.CC(C)(C)OC(=O)CN

InChI

1S/C6H13NO2.ClH/c1-6(2,3)9-5(8)4-7;/h4,7H2,1-3H3;1H

InChIKey

OSWULUXZFOQIRU-UHFFFAOYSA-N

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Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)

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Analysenzertifikate (COA)

Lot/Batch Number
BCBV0393
BCBQ9664V
BCBK0236V
BCBD6677V
BCBD0289V

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S Sarhan et al.
Arzneimittel-Forschung, 34(6), 687-690 (1984-01-01)
The synergistic amplification of the anticonvulsant effects of direct and indirect GABA agonists by glycine has previously been demonstrated. We show in the present report that the anticonvulsant effect of vinyl GABA, a GABA-T (4-aminobutyrate: 2-oxoglutarate aminotransferase) inhibitor with antiepileptic
Baptiste Thierry et al.
Molecular diversity, 9(4), 277-290 (2005-11-29)
Cross-linked polystyrene-bound and poly(ethylene glycol)-bound phase-transfer catalysts as well as homopolymers of cinchona alkaloid derivatives have been synthesised. Both soluble and insoluble polymers have been investigated. The enantioselective alkylation of N-diphenyl methylene glycine t-butyl ester has been successfully carried out
M Nakoji et al.
Organic letters, 3(21), 3329-3331 (2001-10-12)
[reaction: see text]. A chiral phase-transfer catalyst has been applied to the asymmetric allylation of the tert-butyl glycinate-benzophenone Schiff base with various allylic acetates for the first time to give the allylated products in good yields and with comparable to
Ming-Qing Hua et al.
Chemical communications (Cambridge, England), 47(5), 1631-1633 (2010-12-01)
An efficient, catalytic, diastereo- and enantioselective conjugate addition of N-(diphenylmethylene)glycine tert-butyl ester to β-aryl substituted enones was realized in the presence of 1 mol% of newly desired dinuclear N-spiro-ammonium salts, affording functionalized α-amino acid derivatives in 57-98% yields with high
V De Filippis et al.
Biochemistry, 37(39), 13507-13515 (1998-09-30)
Hirudin is the most potent and specific inhibitor of thrombin, a key enzyme in the coagulation process existing in equilibrium between its procoagulant (fast) and anticoagulant (slow) form. In a previous study, we described the solid-phase synthesis of a Trp3
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