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Merck

35586

Supelco

PCB Nr. 1

analytical standard

Synonym(e):

2-Chlor-biphenyl, 2-PCB

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About This Item

Empirische Formel (Hill-System):
C12H9Cl
CAS-Nummer:
Molekulargewicht:
188.65
Beilstein:
1907934
BZ-Nummer:
1
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
41116107
PubChem Substanz-ID:
NACRES:
NA.24

Qualität

analytical standard

Qualitätsniveau

Haltbarkeit

limited shelf life, expiry date on the label

Methode(n)

HPLC: suitable
gas chromatography (GC): suitable

Anwendung(en)

environmental

Format

neat

SMILES String

Clc1ccccc1-c2ccccc2

InChI

1S/C12H9Cl/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10/h1-9H

InChIKey

LAXBNTIAOJWAOP-UHFFFAOYSA-N

Allgemeine Beschreibung

3-Chlorobiphenyl is a chlorinated biphenyl compound, which can be prepared, via phase transfer Gomberg-Bachmann-Hey reaction. It involves the condensation of 3-chlorobenzenediazonium tetrafluoroborate with 18-crown-6 in the presence of potassium acetate.[1]
Polychlorinated biphenyls (PCBs) are a class of highly toxic pollutants found in various environmental matrices and food products. They find a variety of applications as flame retardants, plasticizers, dielectric and heat transfer fluids, etc.[2]

Anwendung

PCB No 1 may be used as an analytical reference standard for the quantification of the analyte in natural matrices using an on-line system for subcritical water extraction combined with high-performance liquid chromatography (HPLC).[3]
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Piktogramme

Health hazardEnvironment

Signalwort

Warning

H-Sätze

Gefahreneinstufungen

Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves


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Analysenzertifikate (COA)

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Christopher P O'Brien et al.
Environmental science & technology, 39(17), 6839-6844 (2005-09-30)
Incineration is commonly used to destroy polychlorinated biphenyl (PCB) wastes, but this method of treatment is not ideal for all mixed liquid wastes, especially those containing radioactive materials. Therefore, other remediation technologies are needed to efficiently treat these waste forms.
Cepanec I
Synthesis of Biaryls, 2010 null
Hyeok Choi et al.
Environmental science & technology, 43(11), 4137-4142 (2009-07-03)
Reactive activated carbon (RAC) impregnated with palladized iron has been developed to effectively treat polychlorinated biphenyls (PCBs) in the environment by coupling adsorption and dechlorination of PCBs. In this study, we addressed the dechlorination reactivity and capacity of RAC toward
On-line coupling of subcritical water extraction with high-performance liquid chromatography via solid-phase trapping
Li B, et al.
Journal of Chromatography A, 873(2), 175-184 (2000)
Yuanxiang Fang et al.
Environmental science & technology, 42(18), 6942-6948 (2008-10-16)
The rate of 2-chlorobiphenyl dechlorination by palladized iron (Fe/ Pd) decreased with increasing pH until pH > 12.5. Iron corrosion potential (Ec) and current (jc), obtained from polarization curves of a rotating disk electrode of iron, followed the Tafel equation

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