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Merck

11223

Supelco

3,3′,5,5′-Tetrabrombisphenol A

analytical standard

Synonym(e):

4,4′-Isopropyliden-bis-(2,6-dibromphenol), TBBPA

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About This Item

Lineare Formel:
(CH3)2C[C6H2(Br)2OH]2
CAS-Nummer:
Molekulargewicht:
543.87
Beilstein:
1889048
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
41116107
PubChem Substanz-ID:
NACRES:
NA.24

Qualität

analytical standard

Qualitätsniveau

Assay

≥97% (HPLC)
96.5-103.5% (wt.)

Haltbarkeit

limited shelf life, expiry date on the label

Methode(n)

HPLC: suitable
gas chromatography (GC): suitable

mp (Schmelzpunkt)

177-183 °C
178-181 °C (lit.)

Anwendung(en)

environmental

Format

neat

SMILES String

CC(C)(c1cc(Br)c(O)c(Br)c1)c2cc(Br)c(O)c(Br)c2

InChI

1S/C15H12Br4O2/c1-15(2,7-3-9(16)13(20)10(17)4-7)8-5-11(18)14(21)12(19)6-8/h3-6,20-21H,1-2H3

InChIKey

VEORPZCZECFIRK-UHFFFAOYSA-N

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Allgemeine Beschreibung

3,3′,5,5′-Tetrabromobisphenol A is a brominated derivative of bisphenol A commonly used as a flame retardant. It finds applications in a variety of consumer products ranging from fabrics to plastics and electronics. Its removal from the aquatic environment using the environmental-friendly chitosan (CS)/poly(vinyl alcohol) (PVA) nanofibrous membranes is reported.

Anwendung

3,3′,5,5′-Tetrabromobisphenol A may be used as an analytical reference standard for the quantification of the analyte in air samples and sediment/sludge samples using chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Verpackung

Bottomless glass bottle. Contents are inside inserted fused cone.

Piktogramme

Health hazardEnvironment

Signalwort

Warning

H-Sätze

Gefahreneinstufungen

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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Analysenzertifikate (COA)

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Die Dokumentenbibliothek aufrufen

An environmentally-friendly enzyme-based nanofibrous membrane for 3, 3?, 5, 5?-tetrabromobisphenol removal
Xu R, et al.
Royal Society of Chemistry Advances, 5(79), 64091-64097 (2015)
Terminal elimination half-lives of the brominated flame retardants TBBPA, HBCD, and lower brominated PBDEs in humans.
Geyer, Harald J., et al.
Organohalogen compounds, 66, 3867-3872 (2004)
Zhiyong Xie et al.
Analytica chimica acta, 584(2), 333-342 (2007-03-28)
A simple and effective method has been developed for analysis of the flame retardant tetrabromobisphenol A (TBBPA) in environmental samples by using modified soxhlet extraction in combination with silica gel clean-up, derivatization with silylation reagent and gas chromatography-mass spectrometry (GC-MS)
Courtney C Carignan et al.
Environmental science & technology, 46(21), 12146-12153 (2012-09-25)
Tetrabromobisphenol-A (TBBP-A) and hexabromocyclododecanes (HBCDs) are brominated flame retardants that have been found in human milk and serum throughout the world, but have received comparatively little attention in the United States. The objective of this study is to determine concentrations
Guillaume ten Dam et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 898, 101-110 (2012-05-18)
Since the EFSA enquired a call for data for TBBPA and HBCD in 2009, the analytical determination of these compounds in food became of regulatory interest. Therefore, a method for the simultaneous determination of TBBPA and the three major HBCD

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