Mori's synthetic works on bioactive natural products in general and pheromones in particular started about 40 years ago to establish their absolute configurations and also to clarify their stereochemistry-bioactivity relationships. Results indicate that bioactive natural products are not always enantiomerically
[reaction: see text] A highly efficient chemical kinetic resolution of bishomoallylic alcohols was developed when the alcohols underwent In(OTf)(3)-catalyzed 3,5-oxonium-ene-type cyclization with steroidal aldehyde 2. Consistently high enantiomeric excess (up to >99%) was obtained.
Bioprocess and biosystems engineering, 34(2), 247-251 (2010-11-04)
The activity of Thermoanaerobium brockii alcohol dehydrogenase (TBADH) adsorbed on mesoporous silica SBA-15 was compared with that of the free enzyme in water and in biphasic system (water phase up to 50% v/v water). TBADH was active at a water
Enzyme and microbial technology, 18(5), 340-346 (1996-04-01)
The fatty acid specificity of lipase from Candida rugosa during the esterification of saturated fatty acids and sulcatol in toluene has been studied. The true kinetic parameters are obtained by fitting the experimental data to a Ping-Pong kinetic model that
Journal of economic entomology, 98(5), 1506-1509 (2005-12-13)
We report here the identification and behavioral activity of volatile compounds emitted by male Platypus mutatus (=sulcatus) Chapuis while boring galleries in living poplar, Populus deltoides Marshall, trees. Headspace analysis using solid phase microextraction techniques showed the presence of 6-methyl-5-hepten-2-ol
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