D62403

1,2-Dichlorethylen, Mischung aus cis und trans

98%

• Synonym(e): 1,2-Dichloroethene, Acetylene dichloride, sym-Dichloroethylene
• Lineare Formel: ClCH=CHCl
• CAS-Nummer: 540-59-0
• Molekulargewicht: 96.94
• EG-Nummer: 208-750-2
• MDL-Nummer: MFCD00062942
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24894013
• NACRES: NA.22

Eigenschaften

• Dampfdruck: 5.32 psi ( 20 °C)
• Qualitätsniveau: 100
• Assay: 98%
• Form: liquid
• Brechungsindex: n20/D 1.447 (lit.)
• bp: 48-60 °C (lit.)
• mp (Schmelzpunkt): −57 °C (lit.)
• Dichte: 1.265 g/mL at 25 °C (lit.)
• SMILES String: Cl\C=C\Cl
• InChI: 1S/C2H2Cl2/c3-1-2-4/h1-2H/b2-1+
• InChIKey: KFUSEUYYWQURPO-OWOJBTEDSA-N

Beschreibung

Allgemeine Beschreibung

1,2-Dichloroethylene, also known as acetylene dichloride, is a chlorinated aliphatic hydrocarbon that is commonly used as an extraction solvent and as a chemical intermediate for other chlorinated solvents and compounds. [1] [2]

Anwendung

1,2-Dichloroethylene, mixture of cis and trans can be used as a reactant to synthesize:

• Chloro-enynes from terminal alkynes via Sonogashira coupling[3].
• Trichloroethyl alkyl ketones by reacting with acyl chlorides via Friedel-Crafts reaction in the presence of aluminum chloride[4].
• (Ethenediyl)bis[thiazole] via Pd-catalyzed Stille-coupling reaction with 2-(tributylstannyl)thiazole[5].

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Danger
• H-Sätze: H225,H332,H412
• P-Sätze: P210 - P233 - P240 - P241 - P273 - P304 + P340 + P312
• Gefahreneinstufungen: Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Flam. Liq. 2
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 2
• Flammpunkt (°F): 42.8 °F - closed cup
• Flammpunkt (°C): 6 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves