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Merck

D28000

Sigma-Aldrich

Diazald®

99%

Synonym(e):

N-Methyl-N-(p-tolylsulfonyl)-nitrosamid, N-Methyl-N-nitroso-p-toluolsulfonamid, N-Nitroso-N-methyl-p-toluolsulfonamid, N-Nitroso-p-toluolsulfomethylamid, p-Tolylsulfomethylnitrosamid, Diazomethan-Ausgangsmaterial

Anmeldenzur Ansicht organisationsspezifischer und vertraglich vereinbarter Preise


About This Item

Lineare Formel:
CH3C6H4SO2N(CH3)NO
CAS-Nummer:
Molekulargewicht:
214.24
Beilstein:
2214345
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.22
Preise und Verfügbarkeit sind derzeit nicht verfügbar.

Qualitätsniveau

Assay

99%

Form

solid

mp (Schmelzpunkt)

61-62 °C (lit.)

SMILES String

CN(N=O)S(=O)(=O)c1ccc(C)cc1

InChI

1S/C8H10N2O3S/c1-7-3-5-8(6-4-7)14(12,13)10(2)9-11/h3-6H,1-2H3

InChIKey

FFKZOUIEAHOBHW-UHFFFAOYSA-N

Anwendung

Nitrosylierungsmittel für Übergangsmetallkomplexe,[1] Amine,[2] und Carbanionen,[3] ebenso eine Vorstufe von Diazomethan.[4]

Lagerung und Haltbarkeit

Warnung: Diese Produkte unterliegen dem Sprengstoffgesetz und müssen gekühlt transportiert werden. Es fallen zusätzliche Transportkosten an.

Rechtliche Hinweise

Diazald is a registered trademark of Merck KGaA, Darmstadt, Germany

Piktogramme

FlameExclamation mark

Signalwort

Danger

Gefahreneinstufungen

Eye Irrit. 2 - Self-react. C - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

4.1A - Other explosive hazardous materials

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

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J. Chem. Soc. Perkin Trans. II, 1233-1233 (1993)
Organometallics, 12, 1029-1029 (1993)
J. Chem. Soc. Perkin Trans. II, 29-29 (1993)
Journal of Chromatographic Science, 29, 8-8 (1991)
Lalit K Golani et al.
Journal of medicinal chemistry, 59(17), 7856-7876 (2016-07-28)
Targeted antifolates with heteroatom replacements of the carbon vicinal to the phenyl ring in 1 by N (4), O (8), or S (9), or with N-substituted formyl (5), acetyl (6), or trifluoroacetyl (7) moieties, were synthesized and tested for selective

Fragen

1-6 von 6 Fragen  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 Antwort
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Hilfreich?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 Antwort
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Hilfreich?

  3. Is Diazald, Product No. D28000 product light-, moisture-, or heat-sensitive?

    1 Antwort
    1. Per the MSDS, this product is light- and heat-sensitive. It may decompose and ignite when stored at a temperature above 40oC.

      Hilfreich?

  4. What solvents can be used to dissolve Product D28000, Diazald®?

    1 Antwort
    1. According to the 13th edition of the chemicals encyclopedia published by the Royal Society of Chemistry, it is soluble in ether, petroleum ether, benzene, chloroform, carbon tetrachloride. It is also soluble in ethanol.

      Hilfreich?

  5. What is the Department of Transportation shipping information for this product?

    1 Antwort
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Hilfreich?

  6. Can Product D28000, Diazald®, be used in mutagenesis studies?

    1 Antwort
    1. Product D28000 (Diazald®) is the suggested alternative for MNNG (1-methyl-3-nitroso-1-nitroguanidine), which has been used for mutagenesis experiments. Unfortunately, Sigma-Aldrich has not tested the affect of Diazald® as a mutagenic agent. It is structurally distinct from MNNG. Products N4766 and N1517 (N-nitroso-N-methylurea), which are recommended for work in mutagenesis, might be more suitable alternatives than product D28000.

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