900714

N-((S)-1-((S)-4-Benzyl-4,5-dihydrooxazol-2-yl)-2,2-dimethylpropyl)acetamide

≥95%

• Synonym(e): Chiral MPAO ligand
• Empirische Formel (Hill-System): C₁₇H₂₄N₂O₂
• CAS-Nummer: 2079094-19-0
• Molekulargewicht: 288.38
• UNSPSC-Code: 12161600

Eigenschaften

• Assay: ≥95%
• Form: powder
• Eignung der Reaktion: reaction type: C-C Bond Formation; reagent type: catalyst; reagent type: ligand; reaction type: C-H Activation
• Funktionelle Gruppe: amide; phenyl
• Lagertemp.: 2-8°C

Beschreibung

Anwendung

Chiral ligand developed by Jin-Quan Yu′s lab for Pd(II)-catalyzed enantioselective β-C(sp³)-H arylation, alkenylation, and alkynylation. This mono-protected aminomethyl oxazoline (MPAO) ligand was used in the challenging desymmetrization of isopropyl groups.

Sonstige Hinweise

Formation of α-chiral centers by asymmetric β-C(sp³)–H arylation, alkenylation, and alkynylation

Sicherheitshinweise

• H-Sätze: H413
• P-Sätze: P273 - P501
• Gefahreneinstufungen: Aquatic Chronic 4
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable