798819

(S)-N-Butyl-1-[(S)-2-((E)-2-hydroxybenzylideneamino)-3-methylbutanoyl]pyrrolidine-2-carboxamide

• Synonym(e): Yoon Anti-[2+2]-Photocycloaddition Ligand
• Empirische Formel (Hill-System): C₂₁H₃₁N₃O₃
• CAS-Nummer: 1613249-59-4
• Molekulargewicht: 373.49
• UNSPSC-Code: 12352111
• PubChem Substanz-ID: 329768671

Eigenschaften

• Form: powder
• Eignung der Reaktion: reaction type: Asymmetric synthesis; reagent type: catalyst; reaction type: Photocatalysis
• Funktionelle Gruppe: amide; amine; imine
• Lagertemp.: 2-8°C
• SMILES String: OC1=C(/C=N/[C@@H](C(C)C)C(N2[C@H](C(NCCCC)=O)CCC2)=O)C=CC=C1
• InChI: 1S/C21H31N3O3/c1-4-5-12-22-20(26)17-10-8-13-24(17)21(27)19(15(2)3)23-14-16-9-6-7-11-18(16)25/h6-7,9,11,14-15,17,19,25H,4-5,8,10,12-13H2,1-3H3,(H,22,26)/b23-14+/t17-,19-/m0/s1
• InChIKey: DULOQBOELOOGIJ-DYOPXDPWSA-N

Beschreibung

Anwendung

Chiral ligand for the asymmetric [2+2] cycloaddition of enones by photoredox catalysis.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Sonstige Hinweise

A Dual-Catalysis Approach to Enantioselective [2 + 2] Photocycloadditions Using Visible Light

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable