75920

OXONE^® Tetrabutylammoniumsalz

technical, ~1.6% active oxygen basis

• Synonym(e): Tetrabutylammonium OXONE^®, Tetrabutylammonium-persulfat Tripelsalz
• CAS-Nummer: 104548-30-3
• Beilstein: 5199887
• UNSPSC-Code: 12352000
• PubChem Substanz-ID: 24886893
• NACRES: NA.22

Eigenschaften

• Qualität: technical
• Form: powder
• Eignung der Reaktion: reagent type: oxidant
• Konzentration: ~1.6% (active oxygen)
• mp (Schmelzpunkt): 144-146 °C
• SMILES String: OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-].CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC
• InChI: 1S/5C16H36N.2H2O5S.2H2O4S/c5*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2*1-5-6(2,3)4;2*1-5(2,3)4/h5*5-16H2,1-4H3;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5
• InChIKey: IGMBKNUVZFAHJM-UHFFFAOYSA-I

Beschreibung

Anwendung

Reagent for:

• Oxidation of Hantzsch 1,4-Dihydropyridines catalyzed by manganese(III) Schiff Base complexes
• Epoxidation of alkenes
• Oxidation of sulfides and olefins
• Oxidation of alcohols
• Oxidation of aromatic amines for synthesis of azoxy arenes

Sonstige Hinweise

Form of Oxone specially suited for the oxidation of sensitive compounds in CH₂Cl₂; Reagent for preparing 2-tetrahydrofuranyl ethers from alcohols and THF by radical coupling

Rechtliche Hinweise

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

Sicherheitshinweise

• Piktogramme: GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H302,H314
• P-Sätze: P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Oral - Skin Corr. 1B
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges