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742945

Sigma-Aldrich

TurboBeads™ TEMPO

≥99%

Synonym(e):

Nanopartikel, magnetisch, TEMPO-modifiziert

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About This Item

UNSPSC-Code:
12352128
NACRES:
NA.22

Produktlinie

TurboBeads™

Assay

≥99%

Form

powder

Zusammensetzung

carbon content, ≤14 wt. %

Eignung der Reaktion

reaction type: solution phase peptide synthesis
reactivity: alcohol reactive

Kennzeichnungsgrad

≥0.1 mmol/g loading (TEMPO)

Magnetisierung

≥120 emu/g, mass saturation

Oberflächenbereich

≥15 m2/g

Durchschnittlicher Durchmesser

≤50 nm

Eignung

conforms to structure for Infrared spectrum

Anwendung

Recyclable TEMPO (2,2,6,6-tetramethylpiperidine 1-oxyl radical)-coated nanoparticles have been prepared by the immobilization of TEMPO on iron oxide (Fe3O4) superparamagnetic nanoparticles.

Verpackung

Bottomless glass bottle. Contents are inside inserted fused cone.

Hinweis zur Analyse

Proof of identity: metallic cobalt identity from XRD

air-stability:
weight gain in air at 400°C >20 wt.%
weight gain in air at 100°C <3 wt.%

Rechtliche Hinweise

TurboBeads is a trademark of TurboBeads LLC

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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Alexander K Tucker-Schwartz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(42), 12718-12726 (2010-09-21)
The organic oxidant TEMPO (2,2,4,4-tetramethylpiperdine-1-oxyl) was immobilized on iron oxide (Fe(3)O(4)) superparamagnetic nanoparticles by employing strong metal-oxide chelating phosphonates and azide/alkyne "click" chemistry. This simple preparation yields recyclable TEMPO-coated nanoparticles with good TEMPO loadings. They have excellent magnetic response and
Quirin M Kainz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(30), 10038-10045 (2013-06-19)
Unprecedented magnetic borohydride exchange (mBER), magnetic Wang aldehyde (mWang) and magnetic amine resins were prepared from highly magnetic polymer-coated cobalt or iron nanoparticles. Microwave irradiation was used to obtain excellent degrees of functionalization (>95 %) and loadings (up to 3.0 mmol  g(-1))
Jacinto Sá et al.
Nanoscale, 5(18), 8462-8465 (2013-07-12)
Non-magnetic Pt catalysts, supported on carbon coated magnetic Co nanoparticles, changed catalytic performance in the presence of an external magnetic field. This behavior relates to an electronic change of Pt induced by a localized magnetic field, which modifies the CO
Vladimir Zlateski et al.
Bioconjugate chemistry, 25(4), 677-684 (2014-03-29)
In the pursuit of robust and reusable biocatalysts for industrial synthetic chemistry, nanobiotechnology is currently taking a significant part. Recently, enzymes have been immobilized on different nanoscaffold supports. Carbon coated metallic nanoparticles were found to be a practically useful support
Inge K Herrmann et al.
Nanoscale, 5(18), 8718-8723 (2013-08-01)
In a number of clinical conditions such as intoxication, bacteraemia or autoimmune diseases the removal of the disease-causing factor from blood would be the most direct cure. However, physicochemical characteristics of the target compounds limit the applicability of classical filtration
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