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734624

Sigma-Aldrich

Cerium(IV)-Oxid-Samarium-dotiert

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<0.5 μm particle size, powder, contains 20 mol % samarium as dopant

Synonym(e):

SDC, Samarium-dotiertes Cer(IV)oxid

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About This Item

Empirische Formel (Hill-System):
CeO2
Molekulargewicht:
172.11
MDL-Nummer:
UNSPSC-Code:
26111700
PubChem Substanz-ID:
NACRES:
NA.23

Form

powder

Enthält

20 mol % samarium as dopant

Zusammensetzung

Sm0.2Ce0.8O1.9

Grünere Alternativprodukt-Eigenschaften

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Oberflächenbereich

10-14 m2/g

Partikelgröße

0.1-0.5 μm (d50)
<0.5 μm

Schüttdichte

1.787 g/mL

Grünere Alternativprodukt-Kategorie

SMILES String

[Sm].O=[Ce]=O

InChI

1S/Ce.2O.Sm

InChIKey

AQGZISMLQKBRRO-UHFFFAOYSA-N

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Allgemeine Beschreibung

Cerium(IV) oxide-samarium doped powder (20% mol samarium doped) (SDC-20) is an electrolytic material with a high oxygen ion conductivity. Samarium ion acts as an aliovalent cation that can be incorporated into the host lattice to increase the oxygen vacancy concentration and improve the oxide ion conduction in cerium oxide. It can be synthesized by reverse strike co-precipitation technique.
Samarium doped ceria may be used as an electrolyte in solid oxide fuel cells (SOFCs). Electrical conductivity as a function of temperature of doped ceria was investigated in a study. Relation of dopant type, oxygen vacancy ordering and ionic conductivity was investigated by transmission electron microscopy and electron energy loss spectroscopy.
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Anwendung

Cerium(IV) oxide-samarium doped can be used in the fabrication of solid oxide fuel cells (SOFCs), which can further be used as environmentally-friendly sources of alternative energy.

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


Analysenzertifikate (COA)

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Hugo J Avila-Paredes et al.
Physical chemistry chemical physics : PCCP, 11(38), 8580-8585 (2009-09-24)
We report a correlation between oxygen ionic conductivity and the enthalpy of formation of trivalent-doped ceria from the component binary oxides observed at relatively low temperatures (150-275 degrees C). The bulk conductivities of La-doped ceria samples identical to those previously
Stephan Immenschuh et al.
Transplantation, 99(1), 56-62 (2014-08-15)
Treatment of patients with antibody-mediated rejection (AMR) after kidney transplantation by rituximab and plasmapheresis is ambiguous. Because of its unknown efficiency and serious side effects, biomarkers, which are predictive for responsiveness to this treatment in AMR patients, are required. Twenty
Intermediate-temperature electrochemical performance of a polycrystalline PrBaCo2O5+ δ cathode on samarium-doped ceria electrolyte.
Chen D, et al.
Journal of Power Sources, 188(1), 96-105 (2009)
Oxygen vacancy ordering in heavily rare-earth-doped ceria.
Ou DR, et al.
Applied Physics Letters, 89(17) (2006)
Jun Zhang et al.
Scientific reports, 4, 7082-7082 (2014-11-19)
In this work, redox-active Mn or Cr is introduced to the B site of redox stable perovskite Sr(0.95)Ti(0.9)Nb(0.1)O3.00 to create oxygen vacancies in situ after reduction for high-temperature CO2 electrolysis. Combined analysis using X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron

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