692336

RuCl₂[(R)−(DM−SEGPHOS^®)][(R,(R))−(DPEN)]

• Synonym(e): Dichlor-[(R)−5,5′−bis-[di-(3,5−xylyl)-phosphino]−4,4′−bi−1,3−benzodioxol]-[(1R,2R)−1,2−diphenylethylendiamin]-ruthenium(II)
• Empirische Formel (Hill-System): C₆₀H₆₀Cl₂N₂O₄P₂Ru
• CAS-Nummer: 944450-45-7
• Molekulargewicht: 1107.05
• MDL-Nummer: MFCD09753031
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329761484
• NACRES: NA.22

Eigenschaften

• Form: powder
• Lagertemp.: 2-8°C
• SMILES String: Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6OCOc6c5-c7c8OCOc8ccc7P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10
• InChI: 1S/C46H44O4P2.C14H16N2.2ClH.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-24H,25-26H2,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1
• InChIKey: FOEKPXQPRAIJRW-ODQAEMFESA-L

Beschreibung

Anwendung

Takasago Ligands and Complexes for Asymmetric Reactions

RuCl₂[(R)-(DM-SEGPHOS^®)][(R,(R))-(DPEN)] can be used as a catalyst in the enantioselective preparation of chiral amino alcohols and their derivatives by asymmetric hydrogenation of various amino ketones using mild hydrogen pressure.[1]

Rechtliche Hinweise

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136 JP Application No. 19970359654

SEGPHOS is a registered trademark of Takasago Intl. Corp.

Sicherheitshinweise

• Lagerklassenschlüssel: 13 - Non Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable