673293

Chloro-(pentamethylcyclopentadienyl)-bis-(triphenylphosphin)-ruthenium(II)

• Synonym(e): Pentamethylcyclopentadienylbis(triphenylphosphin)ruthenium(II)chlorid
• Lineare Formel: [(C₁₀H₁₅)Ru(P((C₆H₅)₃))₂Cl]
• CAS-Nummer: 92361-49-4
• Molekulargewicht: 796.32
• MDL-Nummer: MFCD09038426
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24885155
• NACRES: NA.22

Eigenschaften

• Form: solid
• Qualitätsniveau: 100
• Eignung der Reaktion: core: ruthenium; reagent type: catalyst; reaction type: click chemistry
• mp (Schmelzpunkt): 128 °C (D)
• Lagertemp.: 2-8°C
• SMILES String: Cl[Ru].C[C]1[C](C)[C](C)[C](C)[C]1C.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
• InChI: 1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;;;+1/p-1
• InChIKey: KLXKSZDVKAWYRT-UHFFFAOYSA-M

Beschreibung

Anwendung

Catalyst employed in the cycloaddtion of azides with acetylenes giving exclusively the 1,5-disubstitutedtriazoles in contrast to the 1,4-regiochemistry commonly observed with copper catalysis. Ruthenium catalysis also enables the use of internal acetylenes in these "click cycloaddtions".[1]

Versatile catalyst for living radical polymerization[2]

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable