375233

Dimethyl-3-methylglutarat

99%

• Lineare Formel: CH₃CH(CH₂CO₂CH₃)₂
• CAS-Nummer: 19013-37-7
• Molekulargewicht: 174.19
• MDL-Nummer: MFCD00075608
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24863375
• NACRES: NA.22

Eigenschaften

• Assay: 99%
• Form: liquid
• Brechungsindex: n20/D 1.425 (lit.)
• bp: 110 °C/19 mmHg (lit.)
• Dichte: 1.052 g/mL at 25 °C (lit.)
• SMILES String: COC(=O)CC(C)CC(=O)OC
• InChI: 1S/C8H14O4/c1-6(4-7(9)11-2)5-8(10)12-3/h6H,4-5H2,1-3H3
• InChIKey: YIJLMTNDXYVGPQ-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Dimethyl 3-methylglutarate is an ester. It participates in the synthesis of (R,Z)- muscenone, a valuable perfume ingredient.

Anwendung

Building block for chemoenzymatic asymmetric synthesis.

Dimethyl 3-methylglutarate may be used in the synthesis of (R)- and (S)-4-amino-3-methylbutanoic acids, via initial enantioselective hydrolysis with pig liver esterase. It may be used in the preparation of optically active form of verrucarinic acid derivative. It may be used as building block for chemoenzymatic asymmetric synthesis.

Sicherheitshinweise

• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 206.6 °F - closed cup
• Flammpunkt (°C): 97.00 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves