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Merck

362026

Sigma-Aldrich

Bis(ethylenedithio)tetrathiafulvalen

98%

Synonym(e):

BEDT-TTF, Bi[5,6-dihydro-1,3-dithiolo[4,5-b][1,4]-dithiin-2-yliden]

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About This Item

Empirische Formel (Hill-System):
C10H8S8
CAS-Nummer:
Molekulargewicht:
384.69
Beilstein:
1653830
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23

Assay

98%

Form

solid

mp (Schmelzpunkt)

~260 °C (dec.) (lit.)

SMILES String

C1CSC2=C(S1)S\C(S2)=C3\SC4=C(SCCS4)S3

InChI

1S/C10H8S8/c1-2-12-6-5(11-1)15-9(16-6)10-17-7-8(18-10)14-4-3-13-7/h1-4H2

InChIKey

LZJCVNLYDXCIBG-UHFFFAOYSA-N

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Allgemeine Beschreibung

Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) is an organic superconducting polymer that is used as an electron donor with a superconducting transition temperature (Tc) of 10K.

Anwendung

Used as a component for organic superconductors.
BEDT-TTF may be used as a counter-anion with tetrathiocyanatocuprate which can be prepared by the galvanostatic electrocrystallization process. It may also be used in the preparation of novel paramagnetic conductors by synthesizing multifunctional molecular materials with manganese containing complexes. BEDT-TTF based doping may be used in the fabrication of a hybrid organic change generation layer which can potentially be used in the development of tandem organic light emitting diodes (OLEDs).

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)


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Anion polarity-induced self-doping in a purely organic paramagnetic conductor, α?-α?-(BEDT-TTF) 2 (PO-CONH-m-C6H4SO3)? H2O where BEDT-TTF is bis (ethylenedithio) tetrathiafulvalene and PO is the radical 2, 2, 5, 5-Tetramethyl-3-pyrrolin-1-oxyl.
Akutsu H, et al.
Polyhedron, 136, 23-29 (2017)
Yoshitaka Kawasugi et al.
Science advances, 5(5), eaav7282-eaav7282 (2019-05-17)
A Mott insulator sometimes induces unconventional superconductivity in its neighbors when doped and/or pressurized. Because the phase diagram should be strongly related to the microscopic mechanism of the superconductivity, it is important to obtain the global phase diagram surrounding the
Efficiency enhancement in tandem organic light-emitting devices with a hybrid charge generation layer composed of BEDT-TTF-doped TPBi/mCP/HAT-CN.
Kim DH and Kim TW
Organic Electronics, 15(12), 3452-3457 (2014)
A new compound in the BEDT-TTF family [BEDT-TTF= bis (ethylenedithio) tetrathiafulvalene] with a tetrathiocyanatocuprate (II) anion,(BEDT-TTF) 4 [Cu (NCS) 4].
Faulmann C, et al.
Acta Crystallographica Section E: Crystallographic Communications, 74(12), 1755-1758 (2018)
Péter Szirmai et al.
Proceedings of the National Academy of Sciences of the United States of America, 117(47), 29555-29560 (2020-11-07)
The exotic properties of quantum spin liquids (QSLs) have continually been of interest since Anderson's 1973 ground-breaking idea. Geometrical frustration, quantum fluctuations, and low dimensionality are the most often evoked material's characteristics that favor the long-range fluctuating spin state without

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