277762

(+)-Methyl-D-lactat

98%, optical purity ee: 96% (GLC)

• Synonym(e): D-Methyl lactat, Methyl-(R)-(+)-lactat
• Lineare Formel: CH₃CH(OH)CO₂CH₃
• CAS-Nummer: 17392-83-5
• Molekulargewicht: 104.10
• EG-Nummer: 241-420-6
• MDL-Nummer: MFCD00004517
• UNSPSC-Code: 12352108
• PubChem Substanz-ID: 24856785
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 98%
• Form: liquid
• Optische Aktivität: [α]21/D +8.4°, neat
• Optische Reinheit: ee: 96% (GLC)
• Grünere Alternativprodukt-Eigenschaften: Safer Solvents and Auxiliaries; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Brechungsindex: n20/D 1.413 (lit.)
• bp: 144-145 °C (lit.)
• Dichte: 1.09 g/mL at 25 °C (lit.)
• Grünere Alternativprodukt-Kategorie: , Aligned
• SMILES String: COC(=O)[C@@H](C)O
• InChI: 1S/C4H8O3/c1-3(5)4(6)7-2/h3,5H,1-2H3/t3-/m1/s1
• InChIKey: LPEKGGXMPWTOCB-GSVOUGTGSA-N

Beschreibung

Allgemeine Beschreibung

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry.This compound has benign qualities and is biodegradable, water miscible, and functions as a versatile solvent for CA membrane preparation. This is also used as an intermediate for the production of other chemicals, polymers, and derivatives. Thus this product has been enhanced for Safer solvents and auxiliaries. Click here for more information.

Anwendung

(+)-Methyl D-lactate can be used as a starting material in the asymmetric preparation of:

• Neomethymycin, a macrolide which contains 12-membered macrolactone that is used as a potent biological agent.
• PM-toxin A.

It can also be used as a chiral pool along with D-(-)-tartaric acid in the stereoselective total synthesis of separacenes A and B via Trost-Rychnovsky alkyne rearrangement, Horner-Wadsworth-Emmons olefination as well as Corey-Bakshi-Shibata reaction.

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Warning
• H-Sätze: H226,H319,H335
• P-Sätze: P210 - P233 - P240 - P241 - P242 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 1
• Flammpunkt (°F): 120.2 °F - closed cup
• Flammpunkt (°C): 49 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter