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200050

Sigma-Aldrich

Chrom(III)-chlorid

purified by sublimation, 99%

Synonym(e):

Chromic chloride, Chromium trichloride

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About This Item

Lineare Formel:
CrCl3
CAS-Nummer:
10025-73-7
Molekulargewicht:
158.36
EG-Nummer:
233-038-3
MDL-Nummer:
MFCD00010948
UNSPSC-Code:
12352302
PubChem Substanz-ID:
24851955
NACRES:
NA.23

Assay

99%

Form

flakes

Aufgereinigt durch

sublimation

Eignung der Reaktion

reagent type: catalyst
core: chromium

Verunreinigungen

<0.2% water

Dichte

2.87 g/mL at 25 °C (lit.)

SMILES String

Cl[Cr](Cl)Cl

InChI

1S/3ClH.Cr/h3*1H;/q;;;+3/p-3

InChIKey

QSWDMMVNRMROPK-UHFFFAOYSA-K

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Anwendung

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.2
Chromium(III) chloride can be used in the formation of a catalytic system for the conversion of glucose into 5-hydroxymethylfurfural (HMF). It can also be used in the preparation of ionic liquid mixtures using choline chloride and water with improved ion mobility and conductivity.

Signalwort

Warning

Gefahreneinstufungen

Acute Tox. 4 Oral - Aquatic Chronic 2 - Met. Corr. 1 - Skin Sens. 1B

Lagerklassenschlüssel

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Analysenzertifikate (COA)

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Sigma-Aldrich

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Sigma-Aldrich

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Physicochemical properties of ionic liquid mixtures containing choline chloride, chromium (III) chloride and water: effects of temperature and water content
Protsenko VS, et al.
Ionics, 23(3), 637-643 (2017)
Olivia J Phung et al.
American journal of health-system pharmacy : AJHP : official journal of the American Society of Health-System Pharmacists, 67(7), 535-541 (2010-03-20)
The effect of i.v. chromium administration on glucose control in two patients receiving enteral nutrition is described. Chromium supplementation has been hypothesized to potentiate the actions of insulin in facilitating cellular uptake of glucose. We report two cases-one involving a
J Singh et al.
Toxicological sciences : an official journal of the Society of Toxicology, 45(1), 72-76 (1998-12-16)
Some compounds of hexavalent chromium are well-established carcinogens. Chromium enters mammalian cells in the hexavalent form and is reduced to chromium (III). Treatment of purified DNA with chromium (III) produces DNA-DNA interstrand crosslinks (DDC) which obstruct the progression of DNA
Yu-Fei Song et al.
Dalton transactions (Cambridge, England : 2003), (14)(14), 1864-1871 (2008-03-29)
The coordination chemistry of CrCl3 with three pentadentate ligands having the [1,4,7]-triazacyclononane-1,4-diacetato motif have been investigated. The new resulting six-coordinate Cr(iii)-chloro species react cleanly with sodium azide to form the corresponding azido species, which undergo photolysis under irradiation at 419
Tyler C Drake et al.
Endocrine practice : official journal of the American College of Endocrinology and the American Association of Clinical Endocrinologists, 18(3), 394-398 (2012-02-03)
To investigate the effects of intravenous chromium on serum glucose and insulin infusion rates in hospitalized patients with severe insulin resistance. In this retrospective study, we reviewed hospital records from January 1, 2008, to December 1, 2008, to identify patients
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