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Merck

185310

Sigma-Aldrich

4-Nitroanilin

≥99%

Synonym(e):

1-Amino-4-nitrobenzene, 4-Amino-1-nitrobenzene, 4-Nitro-1-aminobenzene, 4-Nitrobenzenamine, p-Aminonitrobenze

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25,40 €
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44,20 €
500 G
78,50 €

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5 G
25,40 €
100 G
44,20 €
500 G
78,50 €

About This Item

Lineare Formel:
O2NC6H4NH2
CAS-Nummer:
Molekulargewicht:
138.12
Beilstein:
508690
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
eCl@ss:
39032009
PubChem Substanz-ID:
NACRES:
NA.22

25,40 €


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Qualitätsniveau

Assay

≥99%

Form

powder or crystals

bp

260 °C/100 mmHg (lit.)

mp (Schmelzpunkt)

146-149 °C (lit.)

Löslichkeit

ethanol: soluble 25 mg/mL, slightly hazy, yellow to brownish-yellow
water: slightly soluble

Funktionelle Gruppe

nitro

SMILES String

Nc1ccc(cc1)[N+]([O-])=O

InChI

1S/C6H6N2O2/c7-5-1-3-6(4-2-5)8(9)10/h1-4H,7H2

InChIKey

TYMLOMAKGOJONV-UHFFFAOYSA-N

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Allgemeine Beschreibung

4-Nitroaniline forms molecular adducts with 4-amino benzoic acid[1]. It reacts with nitrite ion in hydrochloric acid medium to form 4-nitrophenyldiazonium chloride, which couples with naphth-1-ol in alkaline medium to give a purple azo dye[2]. Photocatalytic degradation of 4-nitroaniline in the presence of TiO2 suspensions in a batch and continuous annular reactor has been studied[3].

Anwendung

Produkt chromogener Reaktionen
4-Nitroaniline can be used to prepare:
  • p

  • -Phenylenediamine using various catalytic systems.[4][5]
  • Poly(4-nitroaniline) thin films for optoelectronic applications.[6]
  • An adduct with picric acid.[7]
  • A crystalline N-(4-nitrophenyl)-β-alanine by reacting with acrylic acid.[8]

Piktogramme

Skull and crossbonesHealth hazard

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - STOT RE 2

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flammpunkt (°F)

415.4 °F - closed cup

Flammpunkt (°C)

213.0 °C - closed cup

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Kunden haben sich ebenfalls angesehen

Crystal and molecular structure of N-(4-nitrophenyl)-?-alanine-Its vibrational spectra and theoretical calculations
Marchewka MK, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 79(4), 758-766 (2011)
A simple and highly efficient route for the preparation of p-phenylenediamine by reducing 4-nitroaniline over commercial CdS visible light-driven photocatalyst in water
Wu W, et al.
Green Chemistry, 14(6), 1705-1709 (2012)
Facile synthesis of spin-coated poly (4-nitroaniline) thin film: Structural and optical properties
Abed-Elmageed AAI, et al.
Optical Materials, 109(6), 110378-110378 (2020)
High efficient photocatalytic reduction of 4-nitroaniline to p-phenylenediamine over microcrystalline SrBi2Nb2O9
Wu W, et al.
Catalysis Communications, 17, 39-42 (2012)
Photocatalytic degradation of 4-nitroaniline using solar and artificial UV radiation.
Gautam S, et al.
Chemical Engineering Journal, 110(1), 129-137 (2005)

Fragen

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 Antwort
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 Antwort
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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