174602

Phenyl-N-phenylphosphoramidochloridat

≥99%

• Synonym(e): N-Phenylphosphoramidochloridic acid phenyl ester
• Lineare Formel: C₆H₅NHP(O)(Cl)OC₆H₅
• CAS-Nummer: 51766-21-3
• Molekulargewicht: 267.65
• EG-Nummer: 257-400-5
• MDL-Nummer: MFCD00003029
• UNSPSC-Code: 12352002
• PubChem Substanz-ID: 24850351
• NACRES: NA.22

Eigenschaften

• Assay: ≥99%
• Form: solid
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling
• mp (Schmelzpunkt): 132-134 °C (lit.)
• SMILES String: ClP(=O)(Nc1ccccc1)Oc2ccccc2
• InChI: 1S/C12H11ClNO2P/c13-17(15,14-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H,(H,14,15)
• InChIKey: ZUQYQPGYEFBITH-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for synthesis of:

• Resin-immobilized actinide ligands
• Carboxylic acid anhydrides and their derivatives
• Thiadiaminooxopyrimidine derivatives for antitumor activity
• Polyanhydrides via dehydrative coupling agents

Reactant for:

• One-pot conversion of pyrimidinones to pyrimidines
• Conversion to alkyl Ph diester

Catalyst for polymerization reactions

Involved in biological studies for chymotrypsin binding and inhibition

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves