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Sigma-Aldrich

Diphenylsilan

97%

Synonym(e):

Diphenyl silane, Diphenylsilicon

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About This Item

Lineare Formel:
(C6H5)2SiH2
CAS-Nummer:
775-12-2
Molekulargewicht:
184.31
Beilstein:
2935887
EG-Nummer:
212-271-4
MDL-Nummer:
MFCD00003002
UNSPSC-Code:
12352103
PubChem Substanz-ID:
24848906
NACRES:
NA.22

Assay

97%

Form

liquid

Brechungsindex

n20/D 1.579 (lit.)

bp

95-97 °C/13 mmHg (lit.)

Dichte

0.993 g/mL at 25 °C (lit.)

SMILES String

[SiH2](c1ccccc1)c2ccccc2

InChI

1S/C12H12Si/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10H,13H2

InChIKey

VDCSGNNYCFPWFK-UHFFFAOYSA-N

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Allgemeine Beschreibung

Diphenylsilane is an organosilicon compound used as an amide bond coupling reagent & alkene hydrosilylation precursor.

Anwendung


  • Preparation of Bis diphenylsilane and Investigation of Its Cationic UV-Curing Material Properties: This study explores the synthesis and photosensitivity of a new material using diphenylsilane, emphasizing its potential in UV-curing applications (Y Liu et al., 2021, MDPI).

  • Inkjet printing of blue phosphorescent light-emitting layer based on bis (3, 5-di (9 H-carbazol-9-yl)) diphenylsilane: Research on the use of diphenylsilane derivatives for developing blue phosphorescent materials for inkjet printing, which could be used in electronic displays (R Bail et al., 2018, RSC Advances).

Zubehör

Produkt-Nr.
Beschreibung
Preisangaben

Lagerklassenschlüssel

10 - Combustible liquids

WGK

WGK 1

Flammpunkt (°F)

208.4 °F - closed cup

Flammpunkt (°C)

98 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

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Diphenylsilane as a coupling reagent for amide bond formation
Sayes, Morgane, et al.
Green Chemistry, 19, 5060-5064 (2017)
Saravanan Karuppiah et al.
ACS nano, 14(9), 12006-12015 (2020-09-10)
Silicon (Si) is the most promising anode candidate for the next generation of lithium-ion batteries but difficult to cycle due to its poor electronic conductivity and large volume change during cycling. Nanostructured Si-based materials allow high loading and cycling stability
Ahmad Arar et al.
Molecules (Basel, Switzerland), 25(7) (2020-04-05)
Currently, Redox Initiating Systems (RISs) of Free Radical Polymerization (FRP) are mainly based on the interaction of aromatic amines with peroxides (e.g., dibenzoyl peroxide (BPO)) that can be both toxic and unstable. In the present work, we aim to replace
Slawomir Rubinsztajn et al.
Macromolecular rapid communications, 42(5), e2000601-e2000601 (2020-12-04)
The reaction of poly(hydromethylsiloxane-co-methylphenylsiloxane) with zirconium (IV) n-propoxide in dry toluene leads to extensive scission of the siloxane chain and conversion of Si-H groups. These processes produce oligomeric siloxanes and organosilanes containing moisture sensitive propoxy and siloxy-zirconate groups. The obtained
Christopher L Rock et al.
Dalton transactions (Cambridge, England : 2003), 48(2), 461-467 (2018-11-30)
The phosphine-substituted α-diimine Ni precursor, (Ph2PPrDI)Ni, has been found to catalyze alkene hydrosilylation in the presence of Ph2SiH2 with turnover frequencies of up to 124 h-1 at 25 °C (990 h-1 at 60 °C). Moreover, the selective hydrosilylation of allylic

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