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72260

Sigma-Aldrich

Nickel(II) perchlorate hexahydrate

purum p.a., crystallized, ≥98.0% (KT)

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About This Item

Linear Formula:
Ni(ClO4)2 · 6H2O
CAS Number:
Molecular Weight:
365.69
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
Assay:
≥98.0% (KT)
form:
crystals

grade

purum p.a.

Assay

≥98.0% (KT)

form

crystals

quality

crystallized

reaction suitability

reagent type: oxidant

mp

140 °C (lit.)

anion traces

chloride (Cl-): ≤500 mg/kg
sulfate (SO42-): ≤500 mg/kg

cation traces

Ca: ≤500 mg/kg
Cd: ≤50 mg/kg
Co: ≤500 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Na: ≤200 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES string

O.O.O.O.O.O.[Ni++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/2ClHO4.Ni.6H2O/c2*2-1(3,4)5;;;;;;;/h2*(H,2,3,4,5);;6*1H2/q;;+2;;;;;;/p-2

InChI key

WHGYCGOFTBFDLW-UHFFFAOYSA-L

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General description

Nickel(II) perchlorate hexahydrate is a hydrated nickel(II) salt.

Application

Nickel(II) perchlorate hexahydrate may be used in the synthesis of tris(2,2′-bipyridylamine)nickel(II) perchlorate[1] and 4,7,7-trimethyl-3,4,5,6,7,8-hexahydrobenzopyran-2(H),5-dione.[2]

Signal Word

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 2 - Ox. Sol. 3 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

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Nickel (II)-2, 2'-dipyridylamine system. I. Synthesis and stereochemistry of the complexes.
Hurley TJ and Robinson MA.
Inorganic Chemistry, 7(1), 33-38 (1968)
A new method for enol lactone synthesis by a Michael addition/cyclization sequence.
Itoh K and Kanemasa S.
Tetrahedron Letters, 44(9), 1799-1802 (2003)

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