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83253

Boron trifluoride - 1-butanol solution

~10% in 1-butanol (∼1.3 M), derivatization grade (GC derivatization), LiChropur

Synonym(s):

BF3 - Butanol solution

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100 mL
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CZK 4,790.00

About This Item

CAS Number:
NACRES:
NA.05
PubChem Substance ID:
UNSPSC Code:
12352200
MDL number:

CZK 4,790.00


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grade

derivatization grade (GC derivatization)

Quality Segment

form

solution

quality

LiChropur, for esterification of fatty acids for GC purposes

reaction suitability

reagent type: derivatization reagent
reaction type: Alkylations

concentration

~10% in 1-butanol (∼1.3 M)

technique(s)

gas chromatography (GC): suitable

density

0.87 g/mL at 20 °C

storage temp.

2-8°C

SMILES string

FB(F)F

InChI

1S/BF3/c2-1(3)4

InChI key

WTEOIRVLGSZEPR-UHFFFAOYSA-N

Application

Learn more in the Product Information
Reagent for the esterification of carboxylic acids for GC analysis
Boron trifluoride-1-butanol solution may be used as a derivatization agent in the separation and identification of water‐soluble low‐molecular‐weight carboxylic acids using capillary electrophoresis (CE) and gas chromatography coupled with mass spectrometry (GC-MS).

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

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157169137987472
form

solution

form

liquid

form

liquid

form

solution

grade

derivatization grade (GC derivatization)

grade

derivatization grade (GC derivatization)

grade

derivatization grade (GC derivatization)

grade

derivatization grade (GC derivatization)

concentration

~10% in 1-butanol (∼1.3 M)

concentration

~10% (~1.3 M)

concentration

11.0-13.0% (alkalimetric), 12% in methanol

concentration

~3 M in 1-butanol

density

0.87 g/mL at 20 °C

density

0.86 g/mL at 20 °C

density

0.875-0.895 g/mL at 20 °C

density

0.87 g/mL at 20 °C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

−20°C

storage temp.

2-8°C

reaction suitability

reagent type: derivatization reagent
reaction type: Alkylations

reaction suitability

reagent type: derivatization reagent
reaction type: Esterifications

reaction suitability

reagent type: derivatization reagent
reaction type: Acylations

reaction suitability

reagent type: derivatization reagent
reaction type: Acylations


signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A - STOT SE 3

target_organs

Central nervous system, Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

95.0 °F - closed cup

flash_point_c

35 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Related Content


Capillary electrophoresis determinative and GC-MS confirmatory method for water-soluble organic acids in airborne particulate matter and vehicle emission.
Dabek-Zlotorzynska E, et al.
Journal of Separation Science, 28(13), 1520-1528 (2005)
Joanna E Rode et al.
Chirality, 24(1), 5-16 (2011-12-06)
Stabilization energies of the electron donor-acceptor sulfinimine···BF(3) complexes calculated at either the B3LYP/aug-cc-pVTZ or the MP2/aug-cc-pVTZ level do not allow to judge, whether the N- or O-atom in sulfinimine is stronger electron-donor to BF(3) . The problem seems to be
Bandna et al.
Natural product research, 23(15), 1445-1450 (2009-10-08)
Acylation of beta-caryophyllene, a sesquiterpene hydrocarbon with acetic anhydride, was carried out under mild catalytic conditions using Lewis acids such as BF3.Et2O, ZnCl2, FeCl3, I2 and AlCl3 as catalysts. Among these, BF3.Et2O was found to catalyse the reaction most efficiently



Global Trade Item Number

SKUGTIN
83253-10ML-F04061838242426
83253-100ML-F04061838110718

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