8.01786

Bromobenzene

for synthesis

• Synonym(s): Bromobenzene, Phenyl bromide
• Empirical Formula (Hill Notation): C₆H₅Br
• CAS Number: 108-86-1
• Molecular Weight: 157.01
• UNSPSC Code: 12352101
• EC Index Number: 203-623-8
• NACRES: NA.22
• MDL number: MFCD00000055
• Assay: ≥99% (GC)
• Form: liquid

Properties

• vapor pressure: 4 hPa ( 20 °C)
• Quality Segment: 200
• assay: ≥99% (GC)
• form: liquid
• autoignition temp.: 565 °C
• potency: 2383 mg/kg LD₅₀, oral (Rat)
• expl. lim.: 0.5-2.5 % (v/v)
• bp: 156 °C/1013 hPa
• mp: -31 °C
• transition temp: flash point 51 °C
• density: 1.49 g/cm³ at 20 °C
• storage temp.: 2-30°C
• SMILES string: Brc1ccccc1
• InChI: 1S/C6H5Br/c7-6-4-2-1-3-5-6/h1-5H
• InChI key: QARVLSVVCXYDNA-UHFFFAOYSA-N

Description

Application

• Synthesis of High-Quality Perovskite Nanocrystals: Utilizing bromobenzene for aliphatic nucleophilic substitution enabled the synthesis of high-quality cesium lead bromide perovskite nanocrystals, which are critical in optoelectronic applications (Li et al., 2019).
• Noncatalytic Bromination of Benzene: This study demonstrated the necessary conditions for the noncatalytic bromination of benzene to produce bromobenzene, providing valuable information for industrial synthesis processes (Shernyukov et al., 2016).

Analysis Note

Assay (GC, area%): ≥ 99 %
Density (d 20 °C/ 4 °C): 1.494 - 1.496
Identity (IR): passes test

Safety Information

• pictograms: GHS02,GHS07,GHS09
• signalword: Warning
• hcodes: H226,H315,H411
• pcodes: P210 - P233 - P240 - P241 - P273 - P303 + P361 + P353
• Hazard Classifications: Aquatic Chronic 2 - Flam. Liq. 3 - Skin Irrit. 2
• Storage Class: 3 - Flammable liquids
• wgk: WGK 2
• flash_point_f: 123.8 °F - closed cup
• flash_point_c: 51.0 °C - closed cup