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Room-temperature Hiyama cross-couplings of arylsilanes with alkyl bromides and iodides.

Journal of the American Chemical Society (2003-05-08)
Jae-Young Lee, Gregory C Fu
ANOTACE

The first method for achieving Hiyama couplings of unactivated alkyl bromides and iodides is reported. The desired carbon-carbon bond formation proceeds under mild conditions (room temperature) with good functional-group tolerance.

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Sigma-Aldrich
Di-tert-butylmethylphosphine, 97%