S4972

Styrene

ReagentPlus^®, contains 4-tert-butylcatechol as stabilizer, ≥99%

• Synonyma: Phenylethylene, Vinylbenzene
• Lineární vzorec: C₆H₅CH=CH₂
• Číslo CAS: 100-42-5
• Molekulová hmotnost: 104.15
• Beilstein/REAXYS Number: 1071236
• EC Number: 202-851-5
• MDL number: MFCD00008612
• UNSPSC Code: 12352100
• PubChem Substance ID: 24899624
• NACRES: NA.21

Vlastnosti

• vapor density: 3.6 (vs air)
• Quality Level: 200
• vapor pressure: 12.4 mmHg ( 37.7 °C); 4.3 mmHg ( 15 °C)
• product line: ReagentPlus^®
• assay: ≥99%
• form: liquid
• autoignition temp.: 914 °F
• contains: 4-tert-butylcatechol as stabilizer
• expl. lim.: 6.1 %
• refractive index: n20/D 1.546 (lit.)
• bp: 145-146 °C (lit.)
• mp: −31 °C (lit.)
• density: 0.906 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: C=Cc1ccccc1
• InChI: 1S/C8H8/c1-2-8-6-4-3-5-7-8/h2-7H,1H2
• InChI key: PPBRXRYQALVLMV-UHFFFAOYSA-N

Popis

General description

Removal of styrene from textile dyeing wastewater treatment plants (TDWTPs) has been investigated. Catalytic potential of the Co-SBA-15 for the oxidation of styrene with hydrogen peroxide has been investigated. Screening of asymmetric epoxidation of styrene by gas chromatography-mass spectrometry (GC-MS) with selected ion monitoring (SIM) has been reported. The homogeneous atom transfer radical polymerization (ATRP) of styrene by employing solubilizing 4,4′-dialkyl substituted 2,2′-bipyridines affords well-defined polymers. The Heck reaction of chlorobenzene and substituted chlorobenzenes with styrene in water using catalytic palladium on carbon affords 1,2-diphenylethane.

Application

Styrene has been used as a test styrene sample in a study involving the effect of reversible addition-fragmentation chain transfer (RAFT) controllers on its RAFT polymerization in supercritical carbon dioxide in the presence of poly(styrene-block-dimethylsiloxane) (PSDMS) as a stabilizer.

Styrene was used in the preparation of well-defined homopolymers, diblock copolymers and triblock copolymers of tert-butyl acrylate, methyl acrylate and styrene.

Other Notes

Inhibitor depletes over time especially at higher temperatures

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Bezpečnostní informace

• pictograms: GHS02,GHS08,GHS07
• signalword: Danger
• hcodes: H226,H304,H315,H319,H332,H335,H361d,H372,H412
• pcodes: P210 - P273 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P312 - P331
• Hazard Classifications: Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3
• target_organs: hearing organs, Respiratory system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 2
• flash_point_f: 89.6 °F - closed cup
• flash_point_c: 32.0 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter