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Merck

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142387

2,4,6-Trimethylpyridine

99%, liquid, ReagentPlus®

Synonyma:

2,4,6-Collidine, sym-Collidine

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Vám/SKUDostupnostCena
5 mL
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751,00 Kč
100 mL
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2 650,00 Kč
500 mL
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11 500,00 Kč
1 L
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18 600,00 Kč
13 950,00 Kč

O této položce

Empirický vzorec (Hillův zápis):
C8H11N
Číslo CAS:
Molekulová hmotnost:
121.18
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-613-3
MDL number:
Beilstein/REAXYS Number:
107283
Assay:
99%
Form:
liquid

751,00 Kč


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Název produktu

2,4,6-Trimethylpyridine, ReagentPlus®, 99%

Quality Segment

product line

ReagentPlus®

assay

99%

form

liquid

refractive index

n20/D 1.498 (lit.)

bp

171-172 °C (lit.)

mp

−43 °C (lit.)

density

0.917 g/mL at 25 °C (lit.)

SMILES string

Cc1cc(C)nc(C)c1

InChI

1S/C8H11N/c1-6-4-7(2)9-8(3)5-6/h4-5H,1-3H3

InChI key

BWZVCCNYKMEVEX-UHFFFAOYSA-N

General description

2,4,6-Trimethylpyridine is a pyridine derivative. It has a pK of 7.4. The product can react with trifluoroiodomethane in cyclopentane solution to afford 1:1 complex. This complex was investigated by NMR (Nuclear Magnetic Resonance) spectroscopy. Collidine-buffered osmium tetroxide solutions have been prepared by adding osmium tetroxide solution to it. These solutions have been used as fixative for electron microscopic studies.
2,4,6-Trimethylpyridine can undergo oxidation with potassium permanganate to form 2,4,6-pyridinetricarboxylic acid.
Hindered base.

Application

2,4,6-Trimethylpyridine (collidine, s-collidine, 2,4,6-collidine) has been used in the preparation of a library of N-acyl aminocoumarins bearing low-molecular-weight N-acyl groups.
Tissue fixative for electron microscopy.
Useful solvent for the cleavage of hindered esters by anhydrous lithium iodide.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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Tato položka
2769028612272515
description

ReagentPlus®, 99%

description

puriss. p.a., 99% (GC)

description

≥90.0%

description

97%

assay

99%

assay

99% (GC)

assay

≥90.0%

assay

97%

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

refractive index

n20/D 1.498 (lit.)

refractive index

n20/D 1.498

refractive index

-

refractive index

-

density

0.917 g/mL at 25 °C (lit.)

density

0.917 g/mL at 25 °C (lit.)

density

0.895 g/mL at 20 °C (lit.)

density

-

bp

171-172 °C (lit.)

bp

171-172 °C (lit.)

bp

-

bp

-

mp

−43 °C (lit.)

mp

−43 °C (lit.)

mp

-

mp

122-125 °C (lit.)


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pictograms

FlameSkull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Skladovací třída

3 - Flammable liquids

wgk

WGK 3

flash_point_f

131.0 °F - closed cup

flash_point_c

55 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Seznamy omezení vyplývajících z předpisů

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108-75-8

CAS No.


Vyberte jednu z posledních verzí:

Osvědčení o analýze (COA)

Lot/Batch Number

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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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