1.01245

Isopentyl nitrite

extra pure stabilized with potassium carbonate

• Synonyma: Isopentyl nitrite, iso-Amyl nitrite, iso-Pentyl nitrite, Nitrous acid isoamyl ester
• Empirický vzorec (Hillův zápis): C₅H₁₁NO₂
• Číslo CAS: 110-46-3
• Molekulová hmotnost: 117.15
• UNSPSC Code: 12352108
• EC Index Number: 203-770-8
• NACRES: NA.22
• MDL number: MFCD00002057

Vlastnosti

• Název produktu: Isopentyl nitrite, extra pure stabilized with potassium carbonate
• SMILES string: N(=O)OCCC(C)C
• InChI: 1S/C5H11NO2/c1-5(2)3-4-8-6-7/h5H,3-4H2,1-2H3
• InChI key: OWFXIOWLTKNBAP-UHFFFAOYSA-N
• form: liquid
• autoignition temp.: 208 °C
• potency: 505 mg/kg LD₅₀, oral (Rat)
• bp: 97-99 °C/1013 hPa
• transition temp: flash point -18 °C
• density: 0.872 g/cm³ at 20 °C
• storage temp.: 2-8°C
• Quality Level: 200

Popis

Analysis Note

Total nitrites (GC): ≥ 97.0 % (a/a)
Identity (IR-spectrum): conforms
Free acid: conforms
Density (d 20 °C/ 4 °C): 0.8720 - 0.8770
Non volatile matter: ≤ 0.04 %

Application

• Deaminative coupling of benzylamines and arylboronic acids: Research demonstrated the use of isopentyl nitrite in the deaminative coupling of benzylamines and arylboronic acids, showcasing its application in creating complex molecules for pharmaceutical and chemical manufacturing processes (Sirvinskaite, Reisenbauer, and Morandi, 2023).
• Syntheses of Arylazo Phosphine Oxides and Phosphonates: Utilizing isopentyl nitrite, research facilitated the synthesis of arylazo phosphine oxides and phosphonates via N-P bond formation under blue LED light conditions, contributing to developments in organophosphorus chemistry (Shen et al., 2022).

Bezpečnostní informace

• pictograms: GHS02,GHS05,GHS07,GHS08
• signalword: Danger
• hcodes: H225 - H302 + H332 - H314 - H317 - H341
• pcodes: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1
• Skladovací třída: 3 - Flammable liquids
• wgk: WGK 3
• flash_point_f: -4.0 °F - closed cup
• flash_point_c: -20 °C - closed cup