T79758

Trimethyl phosphonoacetate

98%

• Synonyma: (Carboxymethyl)phosphonic acid trimethyl ester, NSC 84262
• Lineární vzorec: (CH₃O)₂P(O)CH₂CO₂CH₃
• Číslo CAS: 5927-18-4
• Molekulová hmotnost: 182.11
• UNSPSC Code: 12352108
• NACRES: NA.22
• PubChem Substance ID: 24900489
• EC Number: 227-663-0
• Beilstein/REAXYS Number: 1865177
• MDL number: MFCD00008452
• Assay: 98%

Vlastnosti

• Quality Segment: 200
• assay: 98%
• reaction suitability: reaction type: C-C Bond Formation
• refractive index: n20/D 1.437 (lit.)
• bp: 118 °C/0.85 mmHg (lit.), 265-268 °C (lit.)
• density: 1.125 g/mL at 25 °C (lit.)
• SMILES string: COC(=O)CP(=O)(OC)OC
• InChI: 1S/C5H11O5P/c1-8-5(6)4-11(7,9-2)10-3/h4H2,1-3H3
• InChI key: SIGOIUCRXKUEIG-UHFFFAOYSA-N

Popis

Application

Reactant involved in:

• Intramolecular Mannich-type reactions to produce the sarain A diazatricyclic core
• Organocatalytic oxa-Michael reactions
• Prenylation and geranylation of oxindoles
• Intramolecular Horner-Wadsworth-Emmons reactions
• Olefin cross-metathesis / heterocyclization

Bezpečnostní informace

• Skladovací třída: 10 - Combustible liquids
• Co se děje?: WGK 3
• Bod vzplanutí (°F): 235.4 °F - closed cup
• Bod vzplanutí (°C): 113 °C - closed cup
• PPE (osobní ochranné prostředky): Eyeshields, Gloves, type ABEK (EN14387) respirator filter