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903701

tBuDavePhos Pd G3

powder or crystals, 1:1 THF adduct

Synonyma:

t-BuDavePhos G3 Palladacycle, t-BuDavePhos Palladacycle

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Vám/Skladová položkaDostupnostCena
1 g
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4 750,00 Kč
3 562,50 Kč

O této položce

Lineární vzorec:
C35H45N2O3PPdS · C4H8O
UNSPSC Code:
12161600
NACRES:
NA.22

3 562,50 Kč

Ceníková cena4 750,00 KčUložit 25 %
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Název produktu

tBuDavePhos Pd G3, 1:1 THF adduct

product line

Buchwald precatalyst Generation 3

form

powder or crystals

feature

generation 3

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

functional group

phosphine

SMILES string

CN(C1=C(C2=C(P(C(C)(C)C)C(C)(C)C)C=CC=C2)C=CC=C1)C.NC3=C(C4=C([Pd]OS(C)(=O)=O)C=CC=C4)C=CC=C3.C5COCC5

InChI

1S/C22H32NP.C12H10N.C4H8O.CH4O3S.Pd/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-2-4-5-3-1;1-5(2,3)4;/h9-16H,1-8H3;1-6,8-9H,13H2;1-4H2;1H3,(H,2,3,4);/q;;;;+1/p-1

InChI key

PJRGOORCHKDNHB-UHFFFAOYSA-M

General description

tBuDavePhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has a long life in solutions. tBuDavePhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Application

tBuDavePhos Pd G3 has been used as a precatalyst for the Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids. It may also be used for a variety of C-C and C-N cross-coupling reactions.

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Tato položka
903663762229792357
description

1:1 THF adduct

description

-

description

98%

description

-

reaction suitability

core: palladium, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

reaction suitability

-

reaction suitability

-

form

powder or crystals

form

powder or crystals

form

solid

form

solid

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

product line

Buchwald precatalyst Generation 3

product line

Buchwald precatalyst Generation 4

product line

Buchwald precatalyst Generation 3

product line

Buchwald precatalyst Generation 3

feature

generation 3

feature

generation 4

feature

generation 3

feature

generation 3

Buchwald tBuDavePhos Pd G3 catalyst

1507403-97-5 t-BuDavePhos Pd G4, 4th generation Buchwald precatalyst t-BuDavePhos Pd G4, high purity t-BuDavePhos Pd G4 reagent, t-BuDavePhos Pd G4 chemical structure, t-BuDavePhos Pd G4 cross-coupling catalyst, t-BuDavePhos Pd G4 for organic synthesis, t-BuDavePhos Pd G4 for pharmaceutical applications, t-BuDavePhos Pd G4 lab-grade, t-BuDavePhos Pd G4 palladium catalyst, t-BuDavePhos Pd G4 reaction conditions, t-BuDavePhos Pd G4 solvent compatibility

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Skladovací třída

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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