If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
70956
1-Butyl-3-methylimidazolium hexafluorophosphate
Ekologičtější alternativa
≥97.0% (HPLC)
Synonyma:
BMIMPF6
Vybrat velikost
| Vám/Skladová položka | Dostupnost | Cena |
|---|---|---|
5 g | Obraťte se na zákaznický servis a vyžádejte si informaci o dostupnosti. | 3 130,00 Kč |
50 g | Obraťte se na zákaznický servis a vyžádejte si informaci o dostupnosti. | 7 090,00 Kč |
250 g | Obraťte se na zákaznický servis a vyžádejte si informaci o dostupnosti. | 23 400,00 Kč |
O této položce
3 130,00 Kč
Quality Segment
assay
≥97.0% (HPLC)
form
liquid
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
refractive index
n
density
1.38 g/mL at 20 °C (lit.)
greener alternative category
SMILES string
F[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1
InChI
1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1
InChI key
IXQYBUDWDLYNMA-UHFFFAOYSA-N
General description
1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL). It can be prepared by reacting 1-methylimidazole with chlorobutane. Gaseous hydrofluorocarbons (HFCs) such as fluoromethane, fluoroethane and 1,1,2,2-tetrafluoroethane are soluble in BMIMPF6.
Application
It can also be used as a medium for reactions such as:
- Ring-closing metathesis of diene and enyne substrates in the presence of a novel recyclable ruthenium carbene complex.
- Nickel(II)acetylacetonate catalyzed oxidation of aromatic aldehydes to the corresponding acids using dioxygen as the oxidant.
- Lipase-catalyzed enantioselective acylation of allylic alcohols.
- Allylation of aldehydes using tetraallylstannane to yield homoallylic alcohols.
Features and Benefits
1 of 1
Tato položka | |||
|---|---|---|---|
| description ≥97.0% (HPLC) | description for catalysis, ≥98.5% (T) | description ≥97.0% (HPLC) | description ≥97.0% (HPLC) |
| assay ≥97.0% (HPLC) | assay ≥98.5% (T) | assay ≥97.0% (HPLC) | assay ≥97.0% (HPLC) |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 200 |
| form liquid | form - | form liquid | form solid |
| density 1.38 g/mL at 20 °C (lit.) | density 1.38 g/mL at 20 °C (lit.) | density - | density - |
| refractive index n | refractive index n | refractive index n | refractive index - |
| sustainability Greener Alternative Product | sustainability Greener Alternative Product | sustainability - | sustainability - |
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signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Skladovací třída
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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