Přejít k obsahu
Merck
Všechny fotografie(1)

Key Documents

View All Documentation

524212

Sigma-Aldrich

N-Methyldiphenylamine

96%

Přihlásitk zobrazení cen stanovených pro organizaci a smluvních cen
Všechny fotografie(1)

About This Item

Lineární vzorec:
(C6H5)2NCH3
Číslo CAS:
552-82-9
Molekulová hmotnost:
183.25
EC Number:
209-023-2
MDL number:
MFCD00041900
UNSPSC Code:
12352100
PubChem Substance ID:
24874397
NACRES:
NA.22

Quality Level

100

assay

96%

refractive index

n20/D 1.623 (lit.)

bp

293 °C (lit.)

density

1.05 g/mL at 25 °C (lit.)

SMILES string

CN(c1ccccc1)c2ccccc2

InChI

1S/C13H13N/c1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3

InChI key

DYFFAVRFJWYYQO-UHFFFAOYSA-N

Související kategorie

General description

N-Methyldiphenylamine is an aromatic tertiary amine. It undergoes transformation to N-methylcarbazole (C) via a photochemical reaction.

Application

N-Methyldiphenylamine may be used for the synthesis of phosphonium ion salts. It may also be used as a starting reagent for the preparation of bis(4-carboxyphenyl)-N-methylamine (H2CPMA).

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Osvědčení o analýze (COA)

Vyhledejte osvědčení Osvědčení o analýze (COA) zadáním čísla šarže/dávky těchto produktů. Čísla šarže a dávky lze nalézt na štítku produktu za slovy „Lot“ nebo „Batch“.

Již tento produkt vlastníte?

Dokumenty související s produkty, které jste v minulosti zakoupili, byly za účelem usnadnění shromážděny ve vaší Knihovně dokumentů.

Navštívit knihovnu dokumentů

Zákazníci si také prohlíželi

Slide 1 of 8

1 of 8

4-Ethylcyclohexanone 97%

Sigma-Aldrich

129380

4-Ethylcyclohexanone

Tribenzylamine ≥99.0% (NT)

Sigma-Aldrich

90660

Tribenzylamine

Diphenylamine ACS reagent, ≥99%

Sigma-Aldrich

242586

Diphenylamine

Ethyl linoleate ≥99%

Sigma-Aldrich

L1751

Ethyl linoleate

N-Benzylaniline ≥99%

Sigma-Aldrich

185493

N-Benzylaniline

4-Hydroxybenzhydrazide ≥97%

Sigma-Aldrich

H9882

4-Hydroxybenzhydrazide

9,10-Dibromoanthracene 98%

Sigma-Aldrich

D38855

9,10-Dibromoanthracene

Diphenylamine ReagentPlus®, 99%

Sigma-Aldrich

112763

Diphenylamine

Reaction patterns and kinetics of the photoconversion of N-methyldiphenylamine to N-methylcarbazole.
Forster EW, et al.
Journal of the American Chemical Society, 95(10), 3108-3115 (1973)
Tae Kyung Kim et al.
Inorganic chemistry, 52(2), 589-595 (2012-12-29)
A luminescent lithium metal-organic framework (MOF) is constructed from the solvothermal reaction of Li(+) and a well-designed organic ligand, bis(4-carboxyphenyl)-N-methylamine (H(2)CPMA). A Li-based MOF can detect an explosive aromatic compound containing nitro groups as an explosophore, by showing a dramatic
Frustrated Lewis pair-mediated C?O or C?H bond activation of ethers.
Holthausen MH, et al.
Chemical Communications (Cambridge, England), 50(70), 10038-10040 (2014)
Natália M Monezi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 173, 462-467 (2016-10-08)
The distinct thermochromism observed in solutions containing N,N-dimethylaniline (DMA) and N,N-diethylaniline (DEA) and SO2 was investigated by resonance Raman spectroscopy in a wide range of temperatures. The results indicate in addition to the charge transfer (CT) complexes DMA-SO2 and DEA-SO2
Minoru Yamaji et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 14(9), 1673-1684 (2015-07-07)
Photochemical processes of 4-tert-butyl-4'-methoxydibenzoylmethane (Avobenzone, AB), 4-phenylbenzoylbenzoyl-, 4-phenylbenzoyl-2'-furanyl- and 4-phenylbenzoyl-2'-thenoylmethanes (PB@Ph, PB@F and PB@T, respectively) substituted with Br and Cl at the C2 position were studied by stationary and laser flash photolyses in solution. The absorption spectral features showed that

Náš tým vědeckých pracovníků má zkušenosti ve všech oblastech výzkumu, včetně přírodních věd, materiálových věd, chemické syntézy, chromatografie, analytiky a mnoha dalších..

Obraťte se na technický servis.