This item contains PCL as a component of the PU/PCL copolymer. However, the mol% composition is not determined.
430218
Poly[4,4′-methylenebis(phenyl isocyanate)-alt-1,4-butanediol/di(propylene glycol)/polycaprolactone]
pellets, MDI-polyester/polyether polyurethane.
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O této položce
abrasion resistance
10 mg (Taber, H-22 wheel)
form
beads, pellets
melt index
4 g/10 min (190°C/8.7kg)
hardness
84 (Shore A, ASTM D 2240)
transition temp
Tg −40 °C (DSC), softening point 85 °C (Vicat, ASTM D 1525)
density
1.18 g/mL at 25 °C (lit.)
SMILES string
N(c1ccc(cc1)Cc2ccc(cc2)NC(=O)O)C(=O)O.OCCCCCC(=O)O.OCCCCO.OCCCO
InChI key
UTAMRXGORNGYAA-UHFFFAOYSA-N
General description
Poly[4,4′-methylenebis(phenyl isocyanate)-alt-1,4-butanediol/di(propylene glycol)/polycaprolactone] (PU/PCL) is a polyurethane solution that can be used as a shape memory polymer and a reinforcing unit for enhancing the mechanical and thermal properties of the base materials. It is biocompatible and finds usage in endothelial proliferations. PU/PCL contains polycaprolactone (PCL) that facilitates the hydrophobic properties of the polymeric matrix.
Application
Automotive fascia, cable jackets, side trim, fabric laminates, health care tubing, catheters, transdermal patches and in seals casters, shoes, bushings and wheels.
PU/PCL can be used in the formation of a polyurethane membrane for effective gas separation. It can also be used to synthesize reinforced hydrogel with good thermo-mechanical properties for biomedical applications.
Features and Benefits
Tough, high-performance, wear-resistant elastomer with good clarity, chemical resistance, flexibility and toughness. Can be used in current form or further polymerized. Low compression set
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1
Skladovací třída
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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How much PCL is in the product? In mol%
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How can I determine the shelf life / expiration / retest date of this product?
1 answer-
If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdfHelpful?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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I am curious about what temperature is required for the shape to be remembered and what temperature is required for the shape memory to be expressed.
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The softening point is listed to be approximately 85C. Above this temperature the polymer transitions from a hard, brittle state to a softer, more pliable state. This point is often associated with the onset of significant plastic deformation. Below the softening point, the polymer remains rigid, while above it, the polymer can flow and be molded or shaped. There are no other tests performed regarding the shape memory; any additional testing would need to be performed by the customer.
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