363774

Ethyl 4-bromobenzoate

98%

• Lineární vzorec: BrC₆H₄CO₂C₂H₅
• Číslo CAS: 5798-75-4
• Molekulová hmotnost: 229.07
• NACRES: NA.22
• PubChem Substance ID: 24862216
• UNSPSC Code: 12352100
• EC Number: 227-347-2
• MDL number: MFCD00016329
• Assay: 98%
• Form: liquid

Vlastnosti

• Quality Segment: 200
• assay: 98%
• form: liquid
• refractive index: n20/D 1.544 (lit.)
• bp: 131 °C/14 mmHg (lit.)
• density: 1.403 g/mL at 25 °C (lit.)
• functional group: bromo, ester
• SMILES string: CCOC(=O)c1ccc(Br)cc1
• InChI: 1S/C9H9BrO2/c1-2-12-9(11)7-3-5-8(10)6-4-7/h3-6H,2H2,1H3
• InChI key: XZIAFENWXIQIKR-UHFFFAOYSA-N

Popis

General description

Ethyl 4-bromobenzoate is an ester having electron-withdrawing substituent. It undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported.

Bezpečnostní informace

• Co se děje?: WGK 3
• Skladovací třída: 10 - Combustible liquids
• Bod vzplanutí (°F): >235.4 °F - closed cup
• Bod vzplanutí (°C): > 113 °C - closed cup
• PPE (osobní ochranné prostředky): Eyeshields, Gloves