B56501
4-Bromoanisole
≥99.0%
Synonym(s):
1-Bromo-4-methoxybenzene
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About This Item
Linear Formula:
BrC6H4OCH3
CAS Number:
Molecular Weight:
187.03
Beilstein:
1237590
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
≥99.0%
form
liquid
refractive index
n20/D 1.564 (lit.)
bp
223 °C (lit.)
mp
9-10 °C (lit.)
density
1.494 g/mL at 25 °C (lit.)
SMILES string
COc1ccc(Br)cc1
InChI
1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
InChI key
QJPJQTDYNZXKQF-UHFFFAOYSA-N
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General description
4-Bromoanisole is a useful brominating reagent. It is formed as reaction product in the reaction between HOBr and anisole. Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied. Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate.
Application
4-Bromoanisole was used in the synthesis of aryl 1,3-diketones.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Skin Irrit. 2
Storage Class Code
10 - Combustible liquids
WGK
WGK 2
Flash Point(F)
201.2 °F
Flash Point(C)
94 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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