252387
Pentafluoropropionic anhydride
99%
Synonym(s):
PFPA, Perfluoropropionic anhydride
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About This Item
Linear Formula:
(CF3CF2CO)2O
CAS Number:
Molecular Weight:
310.05
Beilstein:
1806446
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
99%
form
liquid
bp
69-70 °C/735 mmHg (lit.)
density
1.571 g/mL at 25 °C (lit.)
functional group
anhydride
ester
fluoro
SMILES string
FC(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)F
InChI
1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16
InChI key
XETRHNFRKCNWAJ-UHFFFAOYSA-N
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Application
Pentafluoropropionic anhydride was used:
- in preparation of halogenated derivatives of phenolic acids, required for determination of some biologically important acids in cerebrospinal fluid
- as derivatization reagent in detection of 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain by GC-multiple ion detection
- in simultaneous determination of the major metabolites of dopamine in rat striatum by gas-liquid chromatography
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Supplementary Hazards
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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M Kohno et al.
Biochemical and biophysical research communications, 140(1), 448-454 (1986-10-15)
This is the first report to identify 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain. The detection was performed by coupled gas chromatography - multiple ion detection, using heptafluorobutyric anhydride and pentafluoropropionic anhydride as derivatizing reagents. These amines
Simultaneous determination of 3,4-dihydroxyphenylacetic acid and homovanillic acid in milligram amounts of rat striatal tissue by gas-liquid chromatography.
E Watson et al.
Life sciences, 15(12), 2167-2178 (1974-12-15)
Derivatization and gas chromatographic determination of some biologically important acids in cerebrospinal fluid.
E Watson et al.
Analytical biochemistry, 59(2), 441-451 (1974-06-01)
J L Villamor et al.
Journal of analytical toxicology, 29(2), 135-139 (2005-05-21)
A new gas chromatography-mass spectrometry method for the simultaneous identification and quantitation of amphetamine (AP), methamphetamine (MA), 3,4-methylenedioxyamphetamine (MDA), 3,4-methylenedioxymethamphetamine (MDMA), and 3,4-methylenedioxyethamphetamine (MDEA) in hair is proposed. Hair was hydrolyzed in 1 M NaOH at 40 degrees C, subjected
E Ballesteros et al.
Analytical chemistry, 65(13), 1773-1778 (1993-07-01)
A new analytical method that combines on-line derivatization-extraction and gas-liquid chromatography for the determination of N-methylcarbamates is reported. The hydrolysis products of N-methylcarbamates (phenols) are derivatized and extracted in a continuous fashion using pentafluoropropionic anhydride (derivatizing reagent) in n-hexane as
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