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Sigma-Aldrich

Osmium

powder, 99.9% trace metals basis

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About This Item

Empirical Formula (Hill Notation):
Os
CAS Number:
7440-04-2
Molecular Weight:
190.23
EC Number:
231-114-0
MDL number:
MFCD00011147
UNSPSC Code:
11101711
PubChem Substance ID:
24855959
NACRES:
NA.23

Assay

99.9% trace metals basis

form

powder

resistivity

8.12 μΩ-cm, 20°C

bp

5027 °C (lit.)

mp

3045 °C (lit.)

density

22.61 g/cm3 (lit.)

SMILES string

[Os]

InChI

1S/Os

InChI key

SYQBFIAQOQZEGI-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Statements

H228,H315,H318,H335

Hazard Classifications

Eye Dam. 1 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Isolda Romero-Canelón et al.
Journal of medicinal chemistry, 56(3), 1291-1300 (2013-02-02)
Organometallic half-sandwich complexes [M(p-cymene)(azo/imino-pyridine)X](+) where M = Ru(II) or Os(II) and X ═ Cl or I, exhibit potent antiproliferative activity toward a range of cancer cells. Not only are the iodido complexes more potent than the chlorido analogues, but they
Kilian Muñiz
Chemical Society reviews, 33(3), 166-174 (2004-03-18)
Imido complexes of osmium tetroxide are versatile compounds for olefin functionalisation. This tutorial review offers a brief historical overview on these compounds and discusses the electronic properties and reactivities of isolated imido osmium compounds in what had been the original
Michael H Stewart et al.
ACS nano, 6(6), 5330-5347 (2012-06-08)
The ability of luminescent semiconductor quantum dots (QDs) to engage in diverse energy transfer processes with organic dyes, light-harvesting proteins, metal complexes, and redox-active labels continues to stimulate interest in developing them for biosensing and light-harvesting applications. Within biosensing configurations
Hideki Sugimoto et al.
Inorganic chemistry, 52(2), 543-545 (2013-01-01)
Oxidation of the hydroxoosmium(III) complex resulted in C-H bond activation of the methyl group of the supporting ligand (N,N'-dimethyl-2,11-diaza[3.3](2,6)pyridinophane). The product was an osmium(IV) complex exhibiting a seven-coordinate structure with an additional Os-CH(2) bond.
Gabriel E Büchel et al.
Journal of inorganic biochemistry, 113, 47-54 (2012-06-13)
A one-pot synthesis of osmium(IV) complexes with two different tautomers of indazole, 1H-indazole and 2H-indazole, namely (H(2)ind)[Os(IV)Cl(5)(2H-ind)] (1) and (H(2)ind)[Os(IV)Cl(5)(1H-ind)] (2) is reported. Both compounds have been comprehensively characterized by NMR spectroscopy, ESI (electrospray ionization) mass spectrometry, electronic absorption spectroscopy
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