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About This Item
Empirical Formula (Hill Notation):
Ir
CAS Number:
Molecular Weight:
192.22
EC Number:
MDL number:
UNSPSC Code:
12141720
PubChem Substance ID:
NACRES:
NA.23
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Assay
99.9% trace metals basis
form
powder
resistivity
4.71 μΩ-cm
bp
4130 °C (lit.)
mp
2450 °C (lit.)
density
22.65 g/cm3 (lit.)
SMILES string
[Ir]
InChI
1S/Ir
InChI key
GKOZUEZYRPOHIO-UHFFFAOYSA-N
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General description
Iridium is a rare and dense transition metal that belongs to the platinum group of metals and is known for its remarkable physical and chemical properties. Iridium is used in high-temperature applications such as crucibles for crystal growth and in devices that operate under extreme conditions due to its high melting point and stability at elevated temperatures. It is also used in electrical contacts and electrodes because of its excellent corrosion resistance and electrical conductivity. In addition, iridium is used as a catalyst in various organic reactions including hydrogenation, water splitting, C-C coupling, and olefin metathesis.
Application
- Iridium-based double perovskites for efficient water oxidation in acid media: This study highlights the development of iridium-based double perovskites that reduce iridium content while maintaining high activity and stability for water oxidation, significant for energy-related applications in material science (Diaz-Morales et al., 2016).
- Recent advances in understanding oxygen evolution reaction mechanisms over iridium oxide: This paper provides insights into the oxygen evolution reaction (OER) mechanisms on iridium oxide, crucial for improving catalytic processes in industrial applications (Naito et al., 2021).
- Iridium oxide fabrication and application: A review: A comprehensive review that discusses various methods for the fabrication of iridium oxides and their applications, particularly in sensors and catalysts, relevant to both drug discovery and material science (Chen et al., 2020).
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Sol. 1
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
nwg
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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José Luis Núñez-Rico et al.
Organic letters, 15(8), 2066-2069 (2013-04-12)
Iridium(I) complexes of enantiomerically pure phosphine-phosphite ligands ([Ir(Cl)(cod)(P-OP)]) efficiently catalyze the enantioselective hydrogenation of diverse C═N-containing heterocyclic compounds (benzoxazines, benzoxazinones, benzothiazinones, and quinoxalinones; 25 examples, up to 99% ee). A substrate-to-catalyst ratio as high as 2000:1 was reached.
Yuyang Zhou et al.
Chemical communications (Cambridge, England), 49(31), 3230-3232 (2013-03-14)
Five iridium(III) complexes with two N-heterocyclic carbene (NHC) ligands and an ancillary ligand have been designed and successfully synthesized. With multicolor photoluminescence and low toxicity, these carbene complexes were tested, for the first time, as living cell imaging reagents and
Le Guo et al.
Organic letters, 15(5), 1144-1147 (2013-02-16)
The first α-alkylation of unactivated amides with primary alcohols is described. An effective and robust iridium pincer complex has been developed for selective α-alkylation of tertiary and secondary acetamides involving a "borrowing hydrogen" methodology. The method is compatible with alcohols
Shiguang Pan et al.
Organic letters, 15(8), 1902-1905 (2013-04-02)
A cationic Ir(I) complex-catalyzed O-to-N-alkyl migration in 2-alkoxypyridines bearing a secondary alkyl group on the oxygen atom by C-O bond cleavage is described. The present transformation gave various N-alkylpyridones in moderate to good yields. The addition of sodium acetate played
Matthew R Kelley et al.
Inorganic chemistry, 52(5), 2564-2580 (2013-02-21)
A series of seven [Ir{ArNC(NR2)NAr}(cod)] complexes (1a-1g; where R = Me or Et; Ar = Ph, 4-MeC6H4, 4-MeOC6H4, 2,6-Me2C6H3, or 2,6-(i)Pr2C6H3; and cod = 1,5-cyclooctadiene) were synthesized by two different methods from the neutral guanidines, ArN═C(NR2)NHAr, using either MeLi and
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