Saltar al contenido
Merck
Todas las fotos(2)

Documentos clave

Ver Toda la documentación

310700

Sigma-Aldrich

Manganese(IV) oxide

10 μm, reagent grade, ≥90%

Sinónimos:

Manganese dioxide

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización
Todas las fotos(2)

About This Item

Fórmula empírica (notación de Hill):
MnO2
Número de CAS:
1313-13-9
Peso molecular:
86.94
EC Number:
215-202-6
MDL number:
MFCD00003463
UNSPSC Code:
12352303
PubChem Substance ID:
329753639
NACRES:
NA.55

grade

reagent grade

Quality Level

200

assay

≥90%

form

powder

particle size

10 μm

mp

535 °C (dec.) (lit.)

SMILES string

O=[Mn]=O

InChI

1S/Mn.2O

InChI key

NUJOXMJBOLGQSY-UHFFFAOYSA-N

¿Está buscando productos similares? Visita Guía de comparación de productos

General description

Manganese(IV) oxide is an oxidizing reagent that can be used for the oxidation of propargylic alcohols, benzylic or heterocyclic alcohols, saturated alcohols, 1,2-diols, allylic alcohols to α, β-ethylenic aldehydes or ketones, and amines to aldehydes, imines, amides, and diazo compounds. It can also be used for the conversion of allylic alcohols to α, β-ethylenic esters or amides, hydration of nitriles to amides, dehydrogenation and aromatization reactions.

Application


  • High-oxidation-state 3d metal complexes: Explores the catalytic properties of manganese(IV) oxide within high-oxidation-state complexes for advanced organic synthesis, demonstrating its critical role in accelerating chemical reactions and enhancing yield efficiencies, beneficial for pharmaceutical and chemical industries (Cheng J et al., 2018).


  • Synthesis and properties of manganese complexes: Details the synthesis of new manganese complexes that demonstrate unique redox properties, useful for understanding electron transfer processes in various chemical and environmental contexts (Baffert C et al., 2002).


pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - STOT RE 2 Inhalation

target_organs

Brain

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 2

flash_point_f

does not flash

flash_point_c

does not flash

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

Los clientes también vieron

Slide 1 of 3

1 of 3

Lithium manganese(III,IV) oxide electrochemical grade

Sigma-Aldrich

482277

Lithium manganese(III,IV) oxide

Manganese powder, −325 mesh, ≥99% trace metals basis

Sigma-Aldrich

266132

Manganese

Cobalt(II,III) oxide powder, <10 μm

Sigma-Aldrich

221643

Cobalt(II,III) oxide

Manganese dioxide
Cahiez G, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Xing Liu et al.
The Analyst, 137(19), 4552-4558 (2012-08-18)
Inorganic nanomaterials that mimic enzymes are fascinating as they potentially have improved properties relative to native enzymes, such as greater resistance to extremes of pH and temperature and lower sensitivity to proteases. Although many artificial enzymes have been investigated, searching
Highly stretchable alkaline batteries based on an embedded conductive fabric.
Abhinav M Gaikwad et al.
Advanced materials (Deerfield Beach, Fla.), 24(37), 5071-5076 (2012-07-05)
Xin Zhao et al.
ACS nano, 6(6), 5404-5412 (2012-05-05)
Manganese dioxide (MnO(2)) particles 2-3 nm in size were deposited onto a porous "activated microwave expanded graphite oxide" (aMEGO) carbon scaffold via a self-controlled redox process. Symmetric electrochemical capacitors were fabricated that yielded a specific capacitance of 256 F/g (volumetric:
Y Wang et al.
Journal of colloid and interface science, 380(1), 8-15 (2012-06-02)
Bio-inspired chemical approach has been developed for the surface modification and electrophoretic deposition of manganese dioxide and zirconia nanoparticles, prepared by chemical precipitation methods. Caffeic acid, trans-cinnamic acid, p-coumaric acid, and 2,4-dihydroxycinnamic acid were investigated for the surface modification of
Ver todos los artículos relacionados

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

Póngase en contacto con el Servicio técnico