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46437

Supelco

Isoxaflutole

PESTANAL®, analytical standard

Sinónimos:

5-Cyclopropyl-4-[2-(methylsulfonyl)-4-(trifluoromethyl)benzoyl]isoxazole

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About This Item

Fórmula empírica (notación de Hill):
C15H12F3NO4S
Número de CAS:
141112-29-0
Peso molecular:
359.32
Beilstein/REAXYS Number:
8344543
MDL number:
MFCD03095707
UNSPSC Code:
41116107
PubChem Substance ID:
329757183
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

SMILES string

CS(=O)(=O)c1cc(ccc1C(=O)c2cnoc2C3CC3)C(F)(F)F

InChI

1S/C15H12F3NO4S/c1-24(21,22)12-6-9(15(16,17)18)4-5-10(12)13(20)11-7-19-23-14(11)8-2-3-8/h4-8H,2-3H2,1H3

InChI key

OYIKARCXOQLFHF-UHFFFAOYSA-N

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General description

Isoxaflutole is a novel pre-emergence herbicide widely employed for the protection of corn and sugarcane against broadleaf and grass weeds. Its mode of action involves the facilitation of characteristic foliar bleaching activity in target species preceding the plant death.

Application

Isoxaflutole may be used as an analytical reference standard for the determination of the analyte in blackcurrants and soya grain by gas chromatography-tandem mass spectrometry (GC-MS/MS) and liquid chromatography-tandem mass spectrometry (LC-MS/MS), respectively.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Health hazardEnvironment
GHS08,GHS09

signalword

Warning

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
BCCD9420
BCBZ6598
BCBT2782
SZBF317XV
SZB9174XV

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C H Lin et al.
Journal of agricultural and food chemistry, 55(10), 3805-3815 (2007-04-17)
A robust multi-residue procedure is needed for the analysis of the pro-herbicide isoxaflutole and its degradates in soil and plant materials at environmentally relevant (<1 microg kg-1) levels. An analytical method using turbo-spray and heat-nebulizer high-performance liquid chromatography-tandem mass spectrometry
Achim Trebst et al.
Pest management science, 60(7), 669-674 (2004-07-21)
Isoxaflutole or pyrazolate inhibition of tocopherol and plastoquinone biosynthesis in the green alga Chlamydomonas reinhardtii Dang leads to the inactivation of photosystem II and the degradation of its reaction centre D1 protein when exposed to strong light. Cell-permeable short-chain derivatives
C H Lin et al.
Journal of environmental quality, 32(6), 1992-2000 (2003-12-17)
A field lysimeter study with bare ground and five different ground covers was established to evaluate the effect of forage grasses on the fate and transport of two herbicides in leachate. The herbicides were atrazine (ATR; 2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine) and isoxaflutole [IXF;
Chung-Ho Lin et al.
Journal of agricultural and food chemistry, 50(21), 5816-5824 (2002-10-03)
Balance (isoxaflutole, IXF) belongs to a new family of herbicides referred to as isoxazoles. IXF has a very short soil half-life (<24 h), degrading to a biologically active diketonitrile (DKN) metabolite that is more polar and considerably more stable. Further
Garey A Fox et al.
Journal of environmental quality, 33(6), 2281-2289 (2004-11-13)
Macropore flow results in the rapid movement of pesticides to subsurface drains, which may be caused in part by a small portion of macropores directly connected to drains. However, current models fail to account for this direct connection. This research
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