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Merck

33496

Supelco

Flucythrinate

PESTANAL®, analytical standard, mixture of stereo isomers

Sinónimos:

α-Cyano-3-phenoxybenzyl 4-difluoromethoxy-α-isopropylphenylacetate

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About This Item

Fórmula empírica (notación de Hill):
C26H23F2NO4
Número de CAS:
Peso molecular:
451.46
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CC(C)C(C(=O)OC(C#N)c1cccc(Oc2ccccc2)c1)c3ccc(OC(F)F)cc3

InChI

1S/C26H23F2NO4/c1-17(2)24(18-11-13-21(14-12-18)32-26(27)28)25(30)33-23(16-29)19-7-6-10-22(15-19)31-20-8-4-3-5-9-20/h3-15,17,23-24,26H,1-2H3

InChI key

GBIHOLCMZGAKNG-UHFFFAOYSA-N

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General description

Flucythrinate belongs to the class of synthetic pyrethroids, primarily used to control Heliothis spp. in cotton and other insect pests in agricultural crops.

Application

Flucythrinate may be used as a reference standard for the determination of the analyte in milk samples using gas chromatography with electron capture detection (GC-ECD).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

113.0 °F

flash_point_c

45 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

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M Nakata et al.
Pest management science, 57(3), 269-277 (2001-07-18)
A competitive enzyme-linked immunosorbent assay (ELISA) has been developed for the detection of the insecticide flucythrinate in environmental and food samples. Two types of haptens, the acid moiety that is the hydrolyzed product of flucythrinate, and the carboxylated propyl derivative
Corie A Fulton et al.
Environmental toxicology and chemistry, 38(6), 1356-1363 (2019-03-25)
Fluvalinate has been extensively used in the United States to combat honey bee colony loss due to Varroa destructor mites. Our objectives were to investigate the extent of fluvalinate contamination in commercially available wax and to define exposure pathways to
D W Tarry
Veterinary parasitology, 18(3), 229-234 (1985-10-01)
Field trials were carried out from 1980 to 1984 on the use of a controlled-release pesticidal fly control technique on farms in Sussex, England, with a recurrent infectious keratoconjunctivitis problem related to fly attack. Pesticide impregnated p.v.c. ear-tags provided control
Analysis of polychlorinated biphenyls, pyrethroid insecticides and fragrances in human milk using a laminar cup liner in the GC injector.
Zehringer M and Herrmann A
European Food Research and Technology, 212(2), 247-251 (2001)
Maria Fernandez-Alvarez et al.
Rapid communications in mass spectrometry : RCM, 23(23), 3673-3687 (2009-11-10)
The characterization of by-products arising from the UV photodegradation of two insecticide pyrethroids lacking the cyclopropane ring (flucythrinate and fenvalerate) has been investigated by gas chromatography coupled with mass spectrometry (GC/MS). Twenty photoproducts were tentatively identified mainly based on the

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