23182
(+)-1-(9-Fluorenyl)ethyl chloroformate solution
≥18 mM in acetone, for chiral derivatization, LiChropur™
Sinónimos:
(+)-FLEC solution
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About This Item
Fórmula empírica (notación de Hill):
C16H13ClO2
Número de CAS:
Peso molecular:
272.73
MDL number:
UNSPSC Code:
12000000
PubChem Substance ID:
NACRES:
NA.22
Productos recomendados
grade
for chiral derivatization
Quality Level
product line
ChiraSelect™
optical purity
enantiomeric ratio: ≥99.0:1.0 (HPLC)
quality
LiChropur™
concentration
≥18 mM in acetone
technique(s)
HPLC: suitable
refractive index
n20/D 1.359
storage temp.
2-8°C
InChI
1S/C16H13ClO2/c1-10(19-16(17)18)15-13-8-4-2-6-11(13)12-7-3-5-9-14(12)15/h2-10,15H,1H3
InChI key
SFRVOKMRHPQYGE-UHFFFAOYSA-N
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General description
(+)-1-(9-Fluorenyl)ethyl chloroformate [(+)-FLEC] is a chiral derivatizing reagent. It helps in separating enantiomers of α-amino acids, as well as helps in determining its optical purity using HPLC method.
Application
(+)-FLEC may be used in enantioselective analysis of glufosinate using reversed-phase high-performance liquid chromatography system coupled with a fluorescence detection system.
Physical form
Solución en 10 mL de Acetona
Other Notes
Agente derivatizante quiral para aminoácidos primarios y secundarios y aminas. Sus derivados son separados por LC de fase reversa y detección por fluorescencia para su determinación de pureza enantiomérica
Legal Information
ChiraSelect is a trademark of Sigma-Aldrich Co. LLC
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system
supp_hazards
Storage Class
3 - Flammable liquids
wgk_germany
WGK 2
flash_point_f
1.4 °F
flash_point_c
-17 °C
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A Roux et al.
Journal of chromatography, 570(2), 453-461 (1991-10-04)
A method for the determination of the R-(+) and S-(-) enantiomers of propranolol in blood was developed. After extraction with heptane-isopentanol and derivatization with (+)-1-(9-fluorenyl)ethyl chloroformate, excess reagent was removed using solid-phase extraction. The enantiomers were separated on an achiral
Zeineb Aturki et al.
Electrophoresis, 25(4-5), 607-614 (2004-02-26)
The indirect resolution of five beta-adrenoreceptor blocking agents (propranolol, oxprenolol, pindolol, metoprolol, and atenolol) using precolumn derivatization with (+)-1-(9-fluorenyl)ethyl chloroformate (FLEC), and capillary electrochromatography (CEC) is reported. Three octadecylsilanized (ODS) silica gel-based stationary phases, differing in particle diameter and carbon
Sascha Freimüller et al.
Journal of pharmaceutical and biomedical analysis, 30(2), 209-218 (2002-08-23)
An indirect enantioseparation method for robust and precise determination of D-Carnitine (D-C) in L-Carnitine (L-C) in the range of 0.1-1.0% is presented. The method is based on derivatization of Carnitine with (+)-[1-(9-fluorenyl)-ethyl]-chloroformate ((+)-FLEC). The two diastereomers are subsequently separated of
Michelle A Camerino et al.
Organic & biomolecular chemistry, 11(16), 2571-2573 (2013-03-14)
An efficient synthesis of the enantiomers of fluorenylethylchloroformate (FLEC) has been achieved that allows the routine application of the reagent for the resolution of chiral amines including unusual amino acids. The utility of the fluorenylethoxycarbonyl (Feoc) group as a chiral
N Todoroki et al.
Journal of chromatography. B, Biomedical sciences and applications, 728(1), 41-47 (1999-06-24)
The natural occurrence of N-methyl-D-aspartate (NMDA) is limited to the foot muscle of Scapharca broughtonii; it is a well known compound for its neuroexitatory activity. This paper describes a high-performance liquid chromatographic (HPLC) method for the determination of NMDA in
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