T67806

Triisopropyl phosphite

95%

• Sinónimos: Isopropyl phosphite, Tri-2-propyl phosphite, Triisopropoxyphosphine, Tris(isopropyl) phosphite
• Fórmula lineal: [(CH₃)₂CHO]₃P
• Número de CAS: 116-17-6
• Peso molecular: 208.24
• Beilstein/REAXYS Number: 1701528
• EC Number: 204-130-0
• MDL number: MFCD00008874
• UNSPSC Code: 12352100
• PubChem Substance ID: 24900404
• NACRES: NA.22

Propiedades

• vapor pressure: <2 mmHg ( 20 °C)
• Quality Level: 200
• assay: 95%
• refractive index: n20/D 1.411 (lit.)
• bp: 63-64 °C/11 mmHg (lit.)
• density: 0.844 g/mL at 25 °C (lit.)
• SMILES string: CC(C)OP(OC(C)C)OC(C)C
• InChI: 1S/C9H21O3P/c1-7(2)10-13(11-8(3)4)12-9(5)6/h7-9H,1-6H3
• InChI key: SJHCUXCOGGKFAI-UHFFFAOYSA-N

Descripción

Application

Triisopropyl phosphite can be used as a reactant:

• With Ru-based indenylidene complexes to form 1^st generation complexes for metathesis reactions.
• In Perkow-type reaction to synthesize compounds containing polarized carbon-carbon double bonds.
• For the synthesis of phosphonohydrazines by reacting with arylamines and isoamyl nitrite.

It can also be used as an alternative to triphenylphosphine in Mitsunobu reaction to facilitate the isolation of products.

Información de seguridad

• pictograms: GHS06
• signalword: Danger
• hcodes: H301,H315
• pcodes: P301 + P310 + P330 - P302 + P352
• Hazard Classifications: Acute Tox. 3 Oral - Skin Irrit. 2
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 3
• flash_point_f: 154.4 °F - closed cup
• flash_point_c: 68 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter