Saltar al contenido
Merck
Todas las fotos(1)

Key Documents

View All Documentation

157457

Sigma-Aldrich

3,5-Di-tert-butyl-o-benzoquinone

98%

Sinónimos:

3,5-Bis(1,1-dimethylethyl)-3,5-cyclohexadiene-1,2-dione, 3,5-Di-t-butyl-o-quinone, 3,5-Di-tert-butyl-1,2-benzoquinone, 3,5-Di-tert-butyl-o-quinone, 3,5-Di-tert-butylcyclohexa-3,5-diene-1,2-dione, 3,5-Di-tert-butylquinone, 3,5-Ditert-butylcyclohexa-3,5-diene-1,2-dione, 4,6-Di-tert-butyl-1,2-benzoquinone, 4,6-Di-tert-butyl-o-benzoquinone

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización
Todas las fotos(1)

About This Item

Fórmula lineal:
[(CH3)3C]2C6H2(=O)2
Número de CAS:
3383-21-9
Peso molecular:
220.31
Beilstein/REAXYS Number:
2047944
EC Number:
222-189-0
MDL number:
MFCD00001647
UNSPSC Code:
12352100
PubChem Substance ID:
24849680
NACRES:
NA.22

Quality Level

100

assay

98%

form

solid

mp

112-114 °C (lit.)

SMILES string

CC(C)(C)C1=CC(=O)C(=O)C(=C1)C(C)(C)C

InChI

1S/C14H20O2/c1-13(2,3)9-7-10(14(4,5)6)12(16)11(15)8-9/h7-8H,1-6H3

InChI key

NOUZOVBGCDDMSX-UHFFFAOYSA-N

Gene Information

human ... ACHE(43) , BCHE(590) , CES1(1066)

¿Está buscando productos similares? Visita Guía de comparación de productos

Categorías relacionadas

General description

Reactions of the phosphinidene-bridged complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) with 3,5-di-tert-butyl-o-benzoquinone has been reported.

Application

3,5-Di-tert-butyl-o-benzoquinone was used in the preparation of benzoxazoles derivative ligands. It was also used in the preparation of 1,4-benzodioxines via hetero Diels Alder reaction with acyclic dienes.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Elija entre una de las versiones más recientes:

Certificados de análisis (COA)

Lot/Batch Number
0000243793
0000246708
0000234429
MKCG5074
MKBW8205V

¿No ve la versión correcta?

Si necesita una versión concreta, puede buscar un certificado específico por el número de lote.

Busque por un COA

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

Olga Iasco et al.
Inorganic chemistry, 51(4), 2588-2596 (2012-01-12)
Two benzoxazoles derivative ligands were synthesized from the condensation of 3,5-di-tert-butyl-o-benzoquinone (DTBBQ) with ethanolamine or 1,3-diamino-2-hydroxypropane in methanol. Condensation of DTBBQ with ethanolamine gives the expected 5,7-di-tert-butyl-2-methylenhydroxylbenzoxazole (HL1) while with 1,3-diamino-2-hydroxypropane it gives (2-hydroxyethyl-2-{2,4-bis(1,1-dimethylethyl)-1-phenol-6 amino}-2{5,7-di-tert-butyl-benzoxazole}) (H(2)L2) with only one benzoxazole
Akira Kotani et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 19(11), 1473-1476 (2003-12-03)
A disposable voltammetric cell using three pencil leads as working, reference, and counter electrodes was developed for determining the titratable acidity, i.e. the acid content in vinegar. The materials of the pencil leads were graphite-reinforcement carbons (GRCs). A voltammetric determination
Chinmoy Das et al.
Dalton transactions (Cambridge, England : 2003), 46(5), 1439-1448 (2017-01-11)
The reaction of anhydrous MCl
M Angeles Alvarez et al.
Dalton transactions (Cambridge, England : 2003), 41(48), 14498-14513 (2012-10-12)
The title complexes reacted readily with the methylating agents MeI and CF(3)SO(3)Me, chalcogens (O(2), S(8)) and borane adducts BH(3)·L (L = THF, N(t)Bu(3), PPh(3)) to initially give the corresponding neutral or cationic derivatives of the type [Fe(2)Cp(2){μ-P(E)R}(μ-CO)(CO)(2)](n) (Cp = η(5)-C(5)H(5);
Norma A Macías-Ruvalcaba et al.
The journal of physical chemistry. B, 110(43), 22043-22047 (2006-10-27)
The electrochemical reduction of 3,5-di-tert-butyl-1,2-benzoquinone, 1, has been studied in acetonitrile with added 2,2,2-trifluoroethanol, 2. At low concentrations of 2 the reaction proceeds by the following pathway: reduction of the quinone (Q) to its anion radical (Q*-) followed by complexation
Ver todos los artículos relacionados

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

Póngase en contacto con el Servicio técnico