102261
2,6-Dimethylcyclohexanone, mixture of isomers
98%
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About This Item
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assay
98%
refractive index
n20/D 1.447 (lit.)
bp
174-176 °C (lit.)
density
0.925 g/mL at 25 °C (lit.)
functional group
ketone
SMILES string
CC1CCCC(C)C1=O
InChI
1S/C8H14O/c1-6-4-3-5-7(2)8(6)9/h6-7H,3-5H2,1-2H3
InChI key
AILVYPLQKCQNJC-UHFFFAOYSA-N
General description
2,6-Dimethylcyclohexanone, mixture of isomers is a clear, light yellow liquid. The adsorption of traces of 2,6-dimethylcyclohexanone, a volatile organic compound, from liquid toluene was studied. cis- and trans-isomers of 2,6-Dimethylcyclohexanonereacts with hydroxylamine hydrochloride and potassium hydroxide in methanol solution gives cis- and trans-dimethylcyclohexanone oxime .
Application
2,6-Dimethylcyclohexanone was used in tetraoxane synthesis and in evaluation of their anti-malarial activity.
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Photochemistry of Oximes III. The Photochemical Beckmann Rearrangement.
Canadian Journal of Chemistry, 49(17), 2891-2896 (1971)
Adsorption of Volatile Organic Compounds. Experimental and Theoretical Study.
Industrial & Engineering Chemistry Research, 51(51), 16697-16708 (2012)
Journal of medicinal chemistry, 43(6), 1246-1249 (2000-03-29)
Two tetramethyl-substituted dispiro-1,2,4,5-tetraoxanes (7,8,15, 16-tetraoxadispiro[5.2.5.2]hexadecanes) 3 and 4 were designed as metabolically stable analogues of the dimethyl-substituted dispiro-1, 2,4,5-tetraoxane prototype WR 148999 (2). For a positive control we selected the sterically unhindered tetraoxane 5 (7,8,15, 16-tetraoxadispiro[5.2.5.2]hexadecane), devoid of any substituents.
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