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Merck

62393

Sigma-Aldrich

Lithium acetate dihydrate

BioUltra, ≥99.0% (anhydrous)

Sinónimos:

Acetic acid lithium salt

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About This Item

Fórmula lineal:
CH3COOLi · 2H2O
Número de CAS:
Peso molecular:
102.02
Beilstein/REAXYS Number:
3564320
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.26

product line

BioUltra

assay

≥99.0% (anhydrous)

form

solid

impurities

insoluble matter, passes filter test
34.0-37.0% water

pH

6.5-8.5 (25 °C, 1 M in H2O)

mp

53-56 °C (lit.)

solubility

H2O: 1 M at 20 °C, clear, colorless

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤100 mg/kg

cation traces

Al: ≤5 mg/kg
As: ≤0.1 mg/kg
Ba: ≤5 mg/kg
Bi: ≤5 mg/kg
Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Mo: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Sr: ≤5 mg/kg
Zn: ≤5 mg/kg

λ

0.1 M in H2O

UV absorption

λ: 260 nm Amax: <0.04
λ: 280 nm Amax: <0.03

SMILES string

[Li+].[H]O[H].[H]O[H].CC([O-])=O

InChI

1S/C2H4O2.Li.2H2O/c1-2(3)4;;;/h1H3,(H,3,4);;2*1H2/q;+1;;/p-1

InChI key

IAQLJCYTGRMXMA-UHFFFAOYSA-M

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Other Notes

In the preparation of the modified ninhydrin reagent for amino analysis by ion-exchange chromatography; Essential for obtaining a fully soluble dimethyl sulfoxide-buffer mixture and for eliminating possible salt precipitation when the ninhydrin reagent mixes with the sodium citrate-containing effluent from an ion-exchange column.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Amino acid analysis: aqueous dimethyl sulfoxide as solvent for the ninhydrin reaction.
S Moore
The Journal of biological chemistry, 243(23), 6281-6283 (1968-12-10)
Paola Gallardo et al.
Cell reports, 33(6), 108377-108377 (2020-11-12)
Upon acute heat stress (HS), overall mRNA transcription, processing, and export are inhibited, leading to cell growth arrest. However, how cells turn off mRNA metabolism is not fully understood. Here, we show that acute HS results in the segregation and
Wenyi Hua et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 969, 117-122 (2014-08-30)
A highly sensitive, selective, and rugged quantification method was developed and validated for decitabine (5-aza-2'-deoxycytidine) in human plasma treated with 100μg/mL of tetrahydrouridine (THU). Chromatographic separation was accomplished using hydrophilic interaction liquid chromatography (HILIC) and detection used electrospray ionization (ESI)
Tomasz Krawczyk
Rapid communications in mass spectrometry : RCM, 29(23), 2257-2262 (2015-11-03)
Hexamethylene triperoxide diamine (HMTD) is one of the peroxide-based explosives that are difficult to detect using standard analytical methodologies. It was analyzed by electrospray ionization mass spectrometry (ESI-MS) on a UPLC-TOF instrument. Alkali metal salts were used to promote the
Zico Alaia Akbar et al.
Optics express, 23(19), A1280-A1287 (2015-09-26)
A unique, hierarchically structured, aggregated TiO(2) nanowire (A-TiO(2)-nw) is prepared by solvothermal synthesis and used as a dual-functioning photoelectrode in dye-sensitized solar cells (DSSCs). The A-TiO(2)-nw shows improved light scattering compared to conventional TiO(2) nanoparticles (TiO(2)-np) and dramatically enhanced dye

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