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Merck

383058

Sigma-Aldrich

Zinc acetate dihydrate

ACS reagent, ≥98%

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About This Item

Fórmula lineal:
Zn(CH3COO)2 · 2H2O
Número de CAS:
Peso molecular:
219.51
Beilstein/REAXYS Number:
3732513
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NB.24

grade

ACS reagent

assay

≥98%
98.0-101.0% (ACS specification)

form

powder, crystals or chunks

reaction suitability

reagent type: catalyst
core: zinc

impurities

≤0.005% insolubles

pH

6.0-7.0 (25 °C, 5%)

anion traces

chloride (Cl-): ≤5 ppm
sulfate (SO42-): ≤0.005%

cation traces

Ca: ≤0.005%
Fe: ≤5 ppm
K: ≤0.01%
Mg: ≤0.005%
Na: ≤0.05%
Pb: ≤0.002%

SMILES string

O.O.CC(=O)O[Zn]OC(C)=O

InChI

1S/2C2H4O2.2H2O.Zn/c2*1-2(3)4;;;/h2*1H3,(H,3,4);2*1H2;/q;;;;+2/p-2

InChI key

BEAZKUGSCHFXIQ-UHFFFAOYSA-L

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General description

Zinc acetate dehydrate is an organic zinc salt. Its enthalpy of formation has been studied using solution calorimetry. Its vibrational spectra has been analyzed. It decomposes into ZnO (zinc oxide) nanoparticles which has been investigated using time-of-flight secondary ion mass spectrometry (TOF-SIMS). A study on the crystalline structure has revealed that it is monoclinic with space group C2/c.

Application

Zinc acetate dehydrate was used as seeds to grow ZnO nanorods on the microfibers of PET (polyethylene terephthalate) fabric.
It may be used in the synthesis of layered Zn-arylphosphonates with potential application in sorption, ion exchange or catalysis. Also it may be used in the ultrasonic preparation of zinc sulfide nanoparticles coated on silica particles.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Vibrational spectra and structures of zinc carboxylates I. Zinc acetate dihydrate.
Ishioka T, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 54(12), 1827-1835 (1998)
Synthesis and characterization of layered zinc biphenylylenebis (phosphonate) and three mixed-component arylenebis (phosphonate)/phosphates.
Zhang, B. et al.
Inorganic Chemistry, 37(8), 1844-1852 (1998)
In situ thermo-TOF-SIMS study of thermal decomposition of zinc acetate dihydrate.
Ghule AV, et al.
Journal of Mass Spectrometry : Jms, 39(10), 1202-1208 (2004)
Development of superhydrophilic and superhydrophobic polyester fabric by growing Zinc Oxide nanorods.
Ashraf M, et al.
Journal of Colloid and Interface Science, 394, 545-553 (2013)
The crystal structure of zinc acetate dihydrate, Zn(CH3COO)2.2H2O.
Niekerk V, et al.
Acta Crystallographica, 6(8-9), 720-723 (1953)

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